Amy Adams wore a big ball gown with raw edge tulle from Oscar de la Renta.
His wife, played by Amy Adams, sits at his side, looking on nearly emotionless.
Joaquin Phoenix and Amy Adams were also recognised for their work on the film.
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His buddy Pete (John Goodman) begs Gus' daughter, Mickey (Amy Adams), to cover his back.
On Tuesday, fans were treated to their first snatch of dialogue between Superman and his Lois Lane, Amy Adams.
Also in the running for supporting actress are Amy Adams (The Master), Helen Hunt (The Sessions) and Sally Field (Lincoln).
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The other major performers in "Doubt" -- Amy Adams, Philip Seymour Hoffman and Viola Davis -- also were nominated in supporting categories.
She may not have taken home the Oscar for Best Supporting Actress but Amy Adams did score the top spot for most-buzzed-about bling.
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Look at Amy Adams in closeup, for instance, all the scarier for being so perky and correct, her features filling the screen as she quizzes the reprobate.
The young Amy Adams, with her doll-like appearance blue eyes, red hair, very pale skin has what can only be called a gift for portraying generosity, optimism, and cheerfulness.
The role has similarities with the character Amy Adams played so beautifully in "Junebug" -- they're two true believers -- and McAdams might reap some awards recognition herself.
The Master's Paul Thomas Anderson is also recognised in the director and screenwriter categories, with additional nominations going to cast members Joaquin Phoenix, Philip Seymour Hoffman and Amy Adams.
Before the ceremony, stars including Clooney, Affleck, Hugh Jackman, Samuel L. Jackson, Amy Adams and Bradley Cooper braved a chilly rain that turned to snow outside the Royal Opera House.
Best Supporting Actress nominees are: Amy Adams for The Master, Sally Field for Lincoln, Anne Hathaway for Les Miserables, Helen Hunt for The Sessions, and Jacki Weaver for Silver Linings Playbook.
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This tradition made it to the big screen via a movie called Leap Year starring Amy Adams (as a young woman who travels to Dublin to propose to her boyfriend on February 29) and Matthew Goode.
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The better, quieter scenes, between Micky and his girlfriend (Amy Adams), who wants to pull him to safety, seem to hail from a different movie, and it becomes ever harder as the story lurches forward to see where the focus of interest lies.
Amy Adams, who is taking time out from her film career to play the Baker's Wife, proves to be a very good singer who is also at ease onstage, though she lacks the apple-crisp bite of irony that Joanna Gleason brought to the original 1987 Broadway production.
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There's also all to play for in a strong Best Supporting Actress category: Amy Adams and Viola Davies who both give excellent performances in "Doubt" -- particularly stage actress Davies who delivers a scene-stealing performance across from Meryl Streep at the film's climax -- could cancel each other out.
Happily, the leads carry the day: James Marsden as a prince of grinning vanity, Susan Sarandon as the wicked stepmother (although the climax turns her into something else, again unnecessarily), and, above all, Amy Adams, who, in the role of a would-be princess, finds true momentum, not just sappiness, in the farce of innocence.
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