He fell to the fourth ball after tea, bowled by Mahmood off an inside edge.
Simmons, one of a handful of full West Indies internationals in the home side, took full advantage of the conditions to reach his hundred from the first ball after tea.
And Sussex nerves were starting to fray when Rory Hamilton-Brown drove the first ball after tea to point and Luke Wright was taken low down at slip driving hard outside off-stump at Plunkett.
Kevin Pietersen made a patient 41 but fell to Sachin Tendulkar's first ball just before tea, ending a 78 stand from 27 overs with Paul Collingwood (62).
England's three seamers each struck twice and Australia completely lost their way when the ball began to reverse swing after tea, with five wickets tumbling in the final session alone, including two in consecutive Chris Tremlett deliveries.
But Afridi switched Asif to the Pavilion End for the first time three overs before tea and with the last ball of the session the bowler took his first wicket.
Gambhir's 167-ball vigil came to an end 45 minutes after tea when he fell to a return catch by Yardy off a top edge having added 40 in 13 overs for the third wicket with Dravid.
On 20 August 2006 the match was abandoned on day four when Pakistan declined to take the field after tea after earlier being penalised for doctoring the match ball.
To really succeed, the Tea Party needs to do more than just whack the ball.
After tea, Anderson was repaid for his discipline with the old ball when Pomersbach edged a flat-footed drive behind.
However, after tea Lee began to work Atapattu over and he eventually hooked a short ball to Phil Jaques at deep square leg.
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