Calvin Harris and Ellie Goulding's collaboration, I Need Your Love, was next at number five.
Judge Jules, Pete Tong, Fatboy Slim, Calvin Harris and Example are supporting the club.
In the best British male category, he triumphed over Plan B, Olly Murs, Calvin Harris and Richard Hawley.
Beach Break Live was held at Pembrey Country Park and attracted stars like Tinie Tempah and Calvin Harris.
Evolution, the fourth album from JLS took the third spot, ahead of last week's number one Calvin Harris.
Adele led the way, but Mumford and Sons, Calvin Harris and even Ellie Goulding have followed in her footsteps.
Calvin Harris, Richard Hawley, Ben Howard, Olly Murs will compete with Plan B for the best British male title.
Other big names taking to the stage on Sunday included Blondie, My Chemical Romance, Pulp and Scottish talents Calvin Harris and KT Tunstall.
On an Erok-run night expect to hear everything from Daft Punk, Calvin Harris, A-Trak and Lykke Li to Sam Young, Jesse Marco and Jupiter Jazz.
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Williams' contemporary, Kylie Minogue, failed to take the number one spot in the album chart, with her album The Abbey Road Sessions settling for second place behind DJ and songwriter Calvin Harris, with 18 Months.
U.K. club king Calvin Harris trades Rihanna's usual somber synths for disco ecstasy on ''We Found Love, '' a song that builds and builds to a climax that's so arena-ready it practically begs for someone to blow a vuvuzela.
If music is your thing, DJ stars Calvin Harris (his 2012 hit Feel So Close was inescapable) and Major Lazer are headlining several live shows throughout the weekend, including the free X Fest Stage at Buttermilk Mountain on Jan. 26.
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