The Legia Warsaw player took the ball in his stride and, from the edge of the area, produced a sublime chip with the outside of his left boot that arced over Myhill to nestle in the back of the net.
Joe Cole was the orchestrator - the winger finding Kalou with an exquisite cross-field pass with the outside of his boot - and the Ivorian danced past two defenders before sliding into the far corner.
The first try came two minutes later as Michalak put through a kick with the outside of his right boot to the right corner and it fell perfectly for Clerc.
Just past the hour McIndoe's wonderful shot - hit with the outside of boot - narrowly went wide as the Doncaster winger continued to bewitch the Villa defence.
BBC: SPORT | Football | League Cup | Doncaster 3-0 Aston Villa
And they took the lead after 13 minutes in some style, Cohen using the outside of his left boot to curl a shot into the top corner.
Zanetti's Argentine compatriot Diego Milito finished coolly with the outside of his boot on 57 minutes after great work from his captain.
The left-back, on the sprint, brought Terry's ball over the top down first time, stepped inside Cana, and then dinked past keeper Marton Fulop with the outside of his boot.
First Frederic Piquionne had a low shot from 25 yards beaten away by the 26-year-old, before Mexican Pablo Barrera struck a shot with the outside of his boot that had to be tipped over.
Arsenal midfielder Rosicky squandered the first clear-cut chance when he did superbly to break clear behind the Scots defence, but his attempt to curl the ball home with the outside of his boot flew wide from 12 yards.
The striker's spectacular overhead kick from six yards came off the inside of the junction of the bar and post and, as the Dons struggled to clear, Goodwillie's chip set up Swanson for a superb half-volley into the far corner with the outside of his boot.
It started when a deft turn from Lucas Barrios briefly left two Japan defenders foundering but his strike with the outside of his right boot was saved.
Smith was also causing problems, jinking between two Wolves defenders before squaring for Dindane, but his first-time poke with the outside of his right boot was pushed away by Hennessey and Smith smashed his follow-up from an acute angle wide.
The Ospreys started brightly, taking only a minute to gain their first opportunity to earn points, but the normally reliant boot of outside-half James Hook misfired as he sent his penalty wide.
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