Americans Paula Creamer and Christina Kim, Japan's Ai Miyazato and Korea's Hee-Won Han finished joint third.
Brewerton and partner Laura Davies were all square with America's Juli Inkster and Paula Creamer at the 16th hole.
Last year, Paula Creamer and Jiyai Shin played the longest two-player playoff in tour history nine holes before Shin won.
Another teenager, Paula Creamer, moved into fourth after a superb 69, which included an eagle two at the 10th when she holed her eight-iron approach from 132 yards.
In the last group of the day, Cristie Kerr and 19-year-old rookie Paula Creamer levelled the entire match with a one-up win over Sweden's Carin Koch and Scot Catriona Matthew.
Around 1.5 million households, or about 10% of cable subscribers in South Korea, watched South Korean Shin Ji-yai beat Paula Creamer in playoff at the Kingsmill Championship in Williamsburg, Va.
Cristie Kerr and Paula Creamer also shot 68 to tie Webb for the best round of the day and it allowed them to move from a tie for 58th to a tie for 13th.
Daniel also picked 49-year-old Juli Inkster, an eight-time Cup veteran, to make up her team alongside Paula Creamer, Cristie Kerr, Angela Stanford, Kristy McPherson, Nicole Castrale, Brittany Lang, Christina Kim, Morgan Pressel, Brittany Lincicome and Natalie Gulbis.
The top 10 featured just three American players, as 2010 winner Paula Creamer tied for seventh with Japan's Mika Miyazoto while 2007 champion Cristie Kerr and Nicole Castrale were alongside Pak on four over for the tournament.
Paula Creamer, hampered by a shoulder injury from a car accident last week in Thailand, held a share of the lead early in the day but struggled with her putting on the back nine and faded to a 71 to finish third at 13 under.
Any chance that the 2005 Solheim Cup, which starts at Crooked Stick in Indiana on Friday, would be different ended the moment Paula "the Pink Panther" Creamer finished voicing her pre-tournament thoughts.
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