Acetic acid in the vinegar delays stomach-emptying and acts as an antidiuretic, remaining in the hung-over body longer than water, and allowing it to rehydrate by absorbing salt and electrolytes in the brine.
Droitwich Spa became the only salt water spa town in Britain when John Corbett created the first spa, St Andrew's Brine Baths, in 1887 as part of the Raven Hotel.