利用原子转移自由基聚合反应合成溴基聚苯乙烯;
The synthetic method comprises the following steps: (1) utilizing atom transfer radical polymerization to synthesize bromo-polystyrene;
利用原子转移自由基聚合反应合成溴基聚苯乙烯;
The method includes the following steps that: (1) atom transfer radical polymerization is utilized to synthesize bromopolystyrene;
原子转移自由基聚合是一种新的活性自由基聚合方法。
Atom transfer radical polymerization is a new type of living radical polymerization method.
本文综述了表面引发原子转移自由基聚合合成聚合物刷及其最新进展。
This article reviews the progress of the synthesis of polymer brushes using surface-initiated atom transfer radical polymerization.
原子转移自由基聚合(ATRP)是目前实验室最常用的可控聚合方法之一。
Atom Transfer Radical polymerization (ATRP) is one of the most widely used method for controlled polymerization in LABS.
对原子转移自由基聚合技术在合成功能性复杂星形聚合物中的应用进行了展望。
Application of ATRP technology to the synthesis of functional complex star polymers is predicted.
本发明涉及一种原子转移自由基聚合引发体系及其在制备高分子化合物的应用。
This invention relates to an atom transfer radical polymerization initiating system and its application in the preparation of polymers.
对用于原子转移自由基聚合的过渡金属催化剂近年来的研究新进展作出了评述和展望。
The recent progress in transition-metal catalyst used in atom transfer radical polymerization has been reviewed in this article.
紧接着,表面引发甲基丙烯酸聚乙二醇酯(PEGMA)原子转移自由基聚合制备梳型聚合物刷。
The comb copolymer brushes were subsequently prepared via surface-initiated atom transfer radical polymerization of poly (ethylene glycol) methyl ether methacrylate (PEGMA).
通过原子转移自由基聚合(ATRP)制备了含1,1-二苯基乙烯(DPE)侧基的聚苯乙烯。
Polystyrenes with 1,1-diphenylethlene(DPE) pendent groups were synthesized via atom transfer radical polymerization(ATRP).
本发明公开了一种聚丙烯接枝共聚物,由一种原子转移自由基聚合引发剂在温和条件下引发聚合制备。
The polypropylene grafted copolymer is prepared through polymerization under mild condition and initiated with one kind of atom transferring free radical polymerization initiator.
实验结果表明用表面引发原子转移自由基聚合在多孔氧化铝膜内部形成分子印迹聚合物纳米管是可行的。
The experimental results prove that atom transfer radical polymerization route works well in the formation of molecularly imprinted polymer nanotubes within porous alumina template.
通过原子转移自由基聚合可以方便地合成各种结构的模型聚合物,包括嵌段、接枝、星形及超支化共聚物等。
The technique of ATRP has been used to synthesize the model polymer with various structure, block copolymer, graft copolymer, star-shaped polymer and hyperbranched polymer.
本发明公开了一种由点击化学和原子转移自由基聚合(ATRP)同步反应制备网络互穿功能性水凝胶的方法。
The invention discloses a method for preparing network interpenetrating functional aquagel through the click chemistry and the atom transfer radical polymerization (ATRP) synchronous reaction.
通过由对氯甲基苯甲酸引发的苯乙烯原子转移自由基聚合(ATRP)合成了分子量可控、分子量分布窄的新型功能聚合物。
A novel type of functional polymer with designed structure, controlled molecular weight and low polydispersities can be prepared via ATRP (Atom Transfer Radical Polymerization).
原子转移自由基聚合(ATRP)反应是实现活性聚合的一种颇为有效的途径,可以合成分子量可控、分子量分布窄的各种聚合物。
Atom transfer radical polymerization (ATRP), which can yield polymers with controlled molecular weight and low polydispersity, is an effective approach to realize living radical polymerization.
本文对原子转移自由基聚合及其反应机理作了简要介绍,并对其近期进展进行了评述,着重介绍了其在共聚物分子结构设计中的一些应用。
The mechanism of ATRP is introduced briefly in this paper, and the new progresses of ATRP are reviewed, emphasis on the applications of ATRP in copolymer molecular design.
综述了普通自由基聚合和原子转移自由基聚合(ATRP)反应对壳聚糖及其衍生物进行修饰改性的研究现状。着重介绍了ATRP技术在壳聚糖接枝改性方面的应用。
The paper reviewed the modification of chitosan by free radical polymerization and atom transfer radical polymerization(ATRP), emphasized the application of ATRP on graft copolymerization of chitosan.
结果表明原子转移自由基乳液聚合和常规乳液聚合存在着很大的差异,特别在成核机理和动力学方面。
As a result, there were great differences between ATRP and conventional emulsion polymerization, especially the nucleation mechanism and the kinetics.
[13] 何三雄,高保娇,申艳玲。室温下甲基丙烯酸缩水甘油酯的原子转移自由基溶液聚合反应[J]。高分子材料科学与工程,2006,22(5):62-65。
HE S X, GAO B J, SHEN Y L. Atom transfer radical polymerization of glycidyl methacrylate in solution system at room temperature[J]. Polymer Materials Science and Engineering, 2006,22(5):62-65.
[13] 何三雄,高保娇,申艳玲。室温下甲基丙烯酸缩水甘油酯的原子转移自由基溶液聚合反应[J]。高分子材料科学与工程,2006,22(5):62-65。
HE S X, GAO B J, SHEN Y L. Atom transfer radical polymerization of glycidyl methacrylate in solution system at room temperature[J]. Polymer Materials Science and Engineering, 2006,22(5):62-65.
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