In other words, if I have an expression for Q, I know the partition function, and I can calculate it at any temperature.
换句话说,如果我得到了Q的表达式,知道了配分函数,我可以计算它在任意温度下的数值。
Being a hardware-based function, partition mobility is only supported on POWER6 hardware; application mobility is supported on any hardware that supports AIX 6.
作为一种基于硬件的功能,仅在POWER 6硬件上提供了对分区迁移的支持;而所有支持AIX 6的硬件都支持应用程序迁移。
This is the electronic partition function.
这是电子的配分函数。
So we're always writing some molecular partition function.
我们总是写下,一些分子的配分函数。
Also notice one of the other results that you've seen is that you could relate the partition function to a, right?
同时要注意你们曾经看到的另一个结果,是你们可以将,配分函数和A关联起来对吗?
You can also look at the molecular partition function itself.
对单个分子的配分函数本身也适用。
We also know what the vibrational partition function is.
我们也知道振动能的配分函数。
Like I promised, we're going to be able to derive every thermodynamic quantity if we just know the partition function.
就像我说过的,我就可以计算所有的热力学量,如果我知道了配分函数。
Not only that, again, we could get this directly from the molecular partition function up there.
不仅如此,再一次,我们能配分函数,从上面的分子。
So now let's figure out our molecular partition function.
现在我们来计算分子的配分函数。
OK. So this is your molecular partition function.
好,这就是分子配分函数。
Our molecular partition function.
我们的分子配分函数。
So it becomes interesting, then, to figure out, how can we write the Helmholtz free energy in terms of the canonical partition function?
这就让我们开始思考,要怎么来表示亥姆霍兹自由能,用正则配分函数?
Then you can have a partition function for each of these degrees of freedom.
都有对应的配分函数,每个自由度。
So so far, we've written for translation partition function.
我们写过了平动的配分函数。
Q And then, big Q, the canonical partition function for the whole system, it's something that we've been through before.
然后,大,整个系统的正则配分函数,这是我们之前探讨过的。
So last time, then, you saw how from the canonical partition function, you could get something like the energy.
上节课我们看到了如何,从正则配分函数导出,内能等量。
And the system partition function is labeled big Q.
系统的配分函数用Q标记。
And what that means is, in the partition function, which is a sum over all these terms with these Boltzmann factors.
这意味着,配分函数,是带波耳兹曼常数的各项之和。
It's called the canonical partition function.
称为正则配分函数。
The elapsed time for completing the task becomes a function of the partition size f(1,000,000) versus a function of the total number of records to process f(100,000,000).
完成这项任务所耗的时间变成为分区大小的函数f(1,000,000),而不再是要处理的总记录数的函数 f(100,000,000)。
Add as required: Use this option if this device must be present in order for the partition to function.
Addasrequired:如果必须存在此设备该分区才能正常工作,则使用此选项。
We can write the partition function as a sum over energy level.
我们可以把配分函数写成,对能级的求和。
So the molecular partition function is labeled little q.
这里分子的配分函数用q标记。
Now, qi is just the total molecular partition function.
现在qi是分子总配分函数。
You also have the system partition function for the configurations.
同样的,对构型部分,也是分子构型配分函数的N次方。
so what's our molecular partition function for this configurational degree of freedom?
配分函数是什么,这些构型的?
In the configurational partition function.
在构型配分函数中。
Q And now we have our capital Q, our canonical configurational partition function.
现在我们有我们的大,我们的正则构型配分函数。
So now we can just write out the configurational partition function for the molecules and also the canonical partition function for the system.
那么现在我们就能写出,分子构型的配分函数,和系统的正则配分函数。
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