简述了分别以一氧化碳、二氧化碳与甲醇、二甲醚等进行羰基化反应合成碳酸二甲酯(DMC)的研究进展。
Advances in the carbonylation synthesis of dimethyl carbonate (DMC) from methanol or dimethyl ether with carbon monoxide or carbon dioxide were summarized.
本文介绍了合成碳酸二甲酯的原理、工艺路线及研究进展。简述了碳酸二甲酯的主要用途。
The principle, process routes and research progress of synthesis of dimethyl carbonate (DMC) are introduced. In addition, the main USES of DMC are reviewed.
应用红外光谱技术研究了在乙酸锌催化作用下1,5-萘二胺与碳酸二甲酯甲氧基羰基化反应机理。
The methoxycarbonylation mechanism of 1,5-naphthalene diamine with dimethyl carbonate catalyzed by zinc acetate was investigated by Fourier transform infrared spectroscopy.
介绍了碳酸二甲酯与苯酚酯交换合成碳酸二苯酯的反应热力学。
Reaction thermodynamics of diphenyl carbonate (DPC) synthesis by the transesterification reaction from dimethyl carbonate and phenol is introduced.
以负载型氧化物为催化剂,研究了二氧化碳在超临界条件下,与甲醇和环氧丙烷一步合成碳酸二甲酯的反应性能。
A study was made on synthesis of dimethyl carbonate with one step from supercritical carbon dioxide, methanol and propylene oxide over supported oxides.
报道一种在甲醇镁作用下,由二氧化碳及甲醇直接合成碳酸二甲酯的反应过程。
Dimethyl carbonate is synthesized directly from carbon dioxide and methanol in the presence of magnesium methoxide.
综述了碳酸二甲酯-甲醇二元共沸物汽液平衡和分离方法的最新研究进展。
Vapor-liquid equilibria and separation of methanol-dimethyl carbonate azeotrope are(reviewed) in this paper.
在洁净煤、环氧丙烷、碳酸二甲酯、聚醚、异丙苯、丙烯腈、丙二醇醚等项目方面提出了相应的建议。
Specifically, Suggestions for the projects of clean coal, propylene oxide, methyl-carbonate, polyether, cumene, acrylonitrile, propylene glycol ether, etc. were proposed.
介绍了近年来由CO2制取甲醇、二甲醚、 合成气、胺类等化学品的研究新进展。还介绍了由CO2 合成羧酸、 碳酸二甲酯等高附价值产品的新成果。
Recent progress on research of CO2 used for production of various chemicals such as methanol, dimethyl ether, syngas, amines and many kinds of polymers were reviewed.
讨论了碳酸二甲酯的合成工艺,主要介绍氧化羰基合成工艺,并对碳酸二甲酯取代硫酸二甲酯和光气市场的可能性进行了分析。
Synthesis process of dimethyl carbonate is reviewed. Oxidative carbonylation of methanol to DMC and the possibilities of replacement of DMS and COCl_2 by DMC are discussed.
项目内容:利用二氧化碳资源,新建碳酸二甲酯、粒干冰粉、杨酸、质氧化鲜、酸钠、撑脲生产线。
Content of the project: utilize CO2 resource, to set up production lines of methyl carbonate, granular dry ice powder, salicylic acid, sodium carbonate and ethylene urea etc.
项目内容:利用二氧化碳资源,新建碳酸二甲酯、粒干冰粉、杨酸、质氧化鲜、酸钠、撑脲生产线。
Content of the project: utilize CO2 resource, to set up production lines of methyl carbonate, granular dry ice powder, salicylic acid, sodium carbonate and ethylene urea etc.
应用推荐