• The inner electrons are so tightly bound that they are for all intents and purposes, immobilized when it comes to reactivity.

    内部电子被紧紧地束缚着,因此无论怎样,当进行反应时,它都是固定的。

    麻省理工公开课 - 固态化学导论课程节选

  • And, in fact, if any electron comes in their midst, they'll capture it because the binding energy is so high.

    事实上,如果电子从中间进来,它们会捕获它,因为束缚能是如此之大。

    麻省理工公开课 - 固态化学导论课程节选

  • So I said that this technique was used to experimentally determine what the different binding energies or the different ionization energies are for the different states in a multielectron atom.

    我说过,这项技术被用来,在实验上确定多电子原子的,各个不同态相应的束缚能,或者电离能。

    麻省理工公开课 - 化学原理课程节选

  • So, remember when we talk about Coulomb force, what's holding the nucleus and the electron together, there's 2 things we need to think about.

    还记得我们在讨论库仑力的时候,提到是什么将原子核与电子束缚在一起时,有两点需要考虑。

    麻省理工公开课 - 化学原理课程节选

  • And, as I mentioned, we left off and as we started back here to describe the atom and how the atom holds together the nucleus and the electron using classical mechanics.

    我之前提及过,我们上次,讲到应用经典力学如何描述,一个原子以及原子如何把质子,和电子束缚在一起,今天我们要。

    麻省理工公开课 - 化学原理课程节选

  • And so the energy is zero because the electron is no longer bound. It is free.

    所以这个系统能量为0,因为,电子不再受束缚了,它自由了。

    麻省理工公开课 - 固态化学导论课程节选

  • So, if we want to go from that stable state to that less stable state, we need to put in a certain amount of energy to our system, that difference between the free electron and the electron bound to the metal.

    所以,如果我们想使电子,从稳态到达不够稳定的状态,我们需要引入一定数量的,能量到系统中,即自由电子束缚于金属的,电子的能量差。

    麻省理工公开课 - 化学原理课程节选

  • They are good electron donors because the electrons aren't tightly bound.

    它们是很好的电子给体,因为电子没有被牢固地束缚

    麻省理工公开课 - 固态化学导论课程节选

  • And that's going to be equal to the negative the binding energy of 2 s in b, in neutral boron.

    它应该等于中性硼原子中,2,s,电子束缚能的负值。

    麻省理工公开课 - 化学原理课程节选

  • That is to say it is confined to the atom.

    也就是说电子会被束缚在原子内。

    麻省理工公开课 - 固态化学导论课程节选

  • So, that means the electrons are tightly bound.

    所以那意味着这些电子是被紧紧地束缚着的。

    麻省理工公开课 - 固态化学导论课程节选

  • So we can think about what is our most loosely-bound electron, what's that highest energy orbital, and it's going to be the 2 p orbital, that's going to be what's highest in energy.

    我们来想一想,它“束缚得最松“的电子是哪一个,能量最高的轨道是哪一个?,它就是,2,p,轨道,是能量最高的轨道。

    麻省理工公开课 - 化学原理课程节选

  • It makes a lot of sense when we look at it energetically, because if we think about a 1 s core electron, that's going to be held really, really tightly to the nucleus.

    从能量的观点来看这是非常合理的,因为如果我们考虑一下,1,s,芯电子,它会被原子核束缚得非常非常紧。

    麻省理工公开课 - 化学原理课程节选

  • So here we have energy increasing on the y-axis, and you see this straight line at the bottom here is lower down on the graph, and that's the energy of a bound electron, so that's going to be a low stable energy.

    这里我们看到能量沿着y轴增加,而且在这张图片上,这条直线在底部是降低的,那是一个束缚电子的能量,所以那是一个低稳态能量。

    麻省理工公开课 - 化学原理课程节选

  • Core electrons are all those electrons held in really tight with the nucleus in the inner shells, whereas the valence electrons are only those electrons that are in the outer-most shell, or at your highest value of n of the principal quantum number.

    电子是那些,在内壳层被原子核束缚得非常紧的电子,而价电子只包括,最外层的电子,或者说主量子数,n,的值最大的那些电子

    麻省理工公开课 - 化学原理课程节选

  • And what we say when we talk about the delta energy is I E 2 that this is going to be equal to i e 2, or the second ionization energy, or we could say the negative of the binding energy of a 2 s electron in b plus.

    那么我们说,Δ,E,应该等于,或者说第二电离能,也就是正一价硼中,2,s,电子的,束缚能的负值。

    麻省理工公开课 - 化学原理课程节选

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