• "The book is Darwin's Universe: Evolution from A to Z, and it is a life's work,"

    VOA: standard.2009.11.25

  • So we're going to feel a higher z effective in the case of the ion compared to the neutral atom.

    因此,我们在离子中,会比在中性原子中感受到更高的有效核电量。

    麻省理工公开课 - 化学原理课程节选

  • So what we're going to see is less shielding, which means that it will actually feel a higher z effective.

    那么我们将会看到更少的屏蔽,这意味着将会感受到更大的有效核电量。

    麻省理工公开课 - 化学原理课程节选

  • The power of linearity is F=k1+k2 if I come across f of x, y, z equals k1 plus k2, if it is a linear equation, I don't have to go and solve it all over again.

    线性的威力是,一个方程,如果它是个线性方程,那么我就不用再去解他了。

    麻省理工公开课 - 固态化学导论课程节选

  • That statement says, get the value of x, which is this link, and give z a pointer to the same place.

    这个声明的意思是,取得x的值,也就是连接指向的值,然后给z赋予一个指向同样位置的指针。

    麻省理工公开课 - 计算机科学及编程导论课程节选

  • If z is greater than 1, then the real gas means that the atoms and molecules in the real gas are repelling each other and wants to have a bigger volume.

    如果Z大于,说明实际气体的分子间斥力较强,体积比理想气体要大,我们可以查表找到。

    麻省理工公开课 - 热力学与动力学课程节选

  • Z So it would be incorrect to try to assign this to a variable X or Y or Z, because it doesn't actually give me anything back.

    这个是错误的,来赋值这个给变量X或Y或,因为它的确没有返回什么给我。

    哈佛公开课 - 计算机科学课程节选

  • And if we experimentally know z what the ionization energy is, we actually have a way to find out what the z effective will be equal to.

    我们实际上就有了一个办法,去找出有效的,等于多少,我们可以使用这里的方程。

    麻省理工公开课 - 化学原理课程节选

  • If we have a higher z effective, it's pulled in tighter, we have to put in more energy in order to eject an electron, so it turns out that that's why case 2 is actually the lowest energy that we need to put in.

    而如果有效核电量更高,原子核的束缚也就更紧,我们不得不输入更多的能量来打出一个电子,这就是第二种情况,所需要输入的,能量更少的原因。

    麻省理工公开课 - 化学原理课程节选

  • So our minimum that we're going to see is that the smallest we can have for a z effective 1 is going to be equal to 1.

    所以我们能够看到的,最小的有效电荷量,等于。

    麻省理工公开课 - 化学原理课程节选

  • They're less shielded because they're closer to the nucleus, they feel a greater z effective.

    它们受到少的屏蔽,因为它们离原子核更近,它们感觉到一个更大的有效电荷量。

    麻省理工公开课 - 化学原理课程节选

  • So, how many distinct, so again, we're talking about distinct kinetic energies, a spectrum for the element hafnium, 72 and I'll tell you here that it has a z of 72, so you don't have to spend two minutes searching your periodic table.

    好,有多少分立的……还是一样,我们讨论的还是不同的动能,铪元素的光谱中出现,而且我来告诉大家铪的原子序数是,这样你就不用因为在元素周期表中找它,而花费两分钟的时间了。

    麻省理工公开课 - 化学原理课程节选

  • So, why don't you take a look at this and tell me which are possible for a 2 s electron in a lithium atom where z 3 is going to be equal to three?

    你们为什么不看一下这个然后告诉我对,于一个锂原子中的2s电子哪些是可能,的?它的有效电荷量,可能等于?

    麻省理工公开课 - 化学原理课程节选

  • It adds x to y and stores it into z. But if someone wants to be a even a little more snarky, what does this program do?

    它把x加上y,再把结果存到z中,但是如果有人,想要做的有点不合常理点呢,那这个程序会做什么?

    哈佛公开课 - 计算机科学课程节选

  • But what you should be able to do is take a look at a list of answers for what we're saying z effective might be, and determining which ones are possible versus which ones are not possible.

    但是你们应该能够做到的,是看一下这个可能的,有效电荷量的答案列表,并且确定哪些是可能的,哪些是不可能的。

    麻省理工公开课 - 化学原理课程节选

  • Not only are we taking away an electron here, but we're also going to decrease shielding, so the electrons that are already in there are going to feel a higher z effective and will be pulling and the atom will be getting smaller.

    这不只是因为我们拿走了一个电子,还因为我们这样做会减小屏蔽效应,这样留下的电子,将会感受到更大的有效核电量,也就会感受到更强的吸引力,使得原子变得更小。

    麻省理工公开课 - 化学原理课程节选

  • Now, unlike high school math or in algebra Z where you call things X and Y and Z, in programming, in computer science, you're actually dealing with humans where it's useful to have a variable name that's more descriptive than X and Y and Z.

    不像高中数学或者代数中,称为X和Y和,在程序设计和计算机科学里,你实际上是在和人打交道,在这里有个描述性比xyz更强的,变量名称是很重要的。

    哈佛公开课 - 计算机科学课程节选

  • I'm binding a z to be some value, and then I'm going to run this.

    我把z绑定到一个值上,然后运行下代码。

    麻省理工公开课 - 计算机科学及编程导论课程节选

  • We go to n equals two for a fixed value of Z.

    我们对于一个给定的Z值,让n等于。

    麻省理工公开课 - 固态化学导论课程节选

  • So we should be able to calculate a z effective for any atom that we want to talk about, as long as we know what that ionization energy is.

    我们应该可以计算出任何一个,我们想要谈论的原子的有效电荷量,只要我们知道电离能是多少。

    麻省理工公开课 - 化学原理课程节选

  • So it's OK to not specify. I want to point out, pz whether you're in the p x, the p y, or the p z, unless a question specifically m asks you to specify the m sub l, which occasionally will happen, but if it doesn't happen you just write it like this.

    我想指出的是,无论你在px,py或,除非一个问题特别地,让你指出l下面的,这种情况有时会发生,这样就可以了,但是如果它不做要求你们写成。

    麻省理工公开课 - 化学原理课程节选

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