So, let's go ahead and do this and take a look at some of the actual atoms that we can think about and think about them in molecules.
让我们继续来看一看一些我们,能考虑的真实原子,并且考虑它们在分子里面。
All right. So, so far we've looked only at molecules that involve atoms that have only s orbitals in them.
好,目前为止我们看的,分子都仅仅包含了s轨道。
The atoms or molecules in the gas don't know that there are other atoms and molecules in the gas, and then you end up with this universal property. All right, so gases that have this universal property, even when the pressure is not zero, those are the ideal gases.
可以忽略,这样就得到了理想气体的性质,在有限压强下,依然能保持这些性质的气体,被称为理想气体,本课中我们把大部分气体,都作为理想气体来处理。
So we'll start to look at molecules and we'll see if we take two atoms and we fill in our molecular orbital and it turns out that they have more anti-bonding orbitals than bonding, that's -- a diatomic molecule we'll never see.
我们要看开始看一看分子,并且我们会发现如果我们,取两个原子并且填入分子轨道,结果是它们的反键轨道,比成键轨道更多,这就是-一个我们不会看到的二元子分子。
And where we had left off was we were going to start one example of thinking about now where we have a heteronuclear diatomic molecules, so two different atoms in terms of forming the molecule.
我们还剩下一个,异核双原子分子的例子没讲,这里组成分子的原子,是不同的。
And then V minus the excluded volume term is equal to RT. Two parameters, this is the attraction between two atoms or molecules in the gas phase.
以及V减去一个排斥项,等于RT,两个参数,这是气体状态下两个原子,或者分子之间的吸引力。
If z is greater than 1, then the real gas means that the atoms and molecules in the real gas are repelling each other and wants to have a bigger volume.
如果Z大于,说明实际气体的分子间斥力较强,体积比理想气体要大,我们可以查表找到。
So what I want to point out with this case in beryllium is that you don't have to use all of the electrons to figure out the bond order, and in fact, once you get to molecules 10 that are from atoms with atomic numbers of 8 or 10, you're not going to want to maybe draw out the full molecular orbital diagram.
我要指出的是,在Be这种情况下,你不需要利用,所有的电子来指导键序,实际上,一旦分子中,原子序数到达了8或者,你也许不想画出,整个分子轨道图。
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