• He said that the percent ionic character, and this is within a bond, not for a compound, for a covalent bond.

    他提到离子百分数,是指一根键中,并非一个分子中。

    麻省理工公开课 - 固态化学导论课程节选

  • CO Right, so you take the co here, and we take the valence here, and out of that comes covalent.

    好了,然后我们看到,我们可以看到他的化合价,他们成共价键。

    麻省理工公开课 - 固态化学导论课程节选

  • A covalent bond is any time we have a pair of electrons that is shared between two different atoms.

    所谓共价键就是我们有两个原子,共用一对电子。

    麻省理工公开课 - 化学原理课程节选

  • There's not actually chemical covalent bonds that are formed but it's a non-covalent interaction, usually dominated by hydrogen bonding.

    所以配体和受体之间不生成共价键,这是一种非共价化合反应,它们通常以氢键相联

    耶鲁公开课 - 生物医学工程探索课程节选

  • OK, so what we've gone through today is we've introduced covalent bonding, and we've figured out a way to quantify it.

    好的,那么我们已经经历了,是我们已经介绍了共价键,我们已经想出了一种定量的方法来。

    麻省理工公开课 - 固态化学导论课程节选

  • Likewise, the element that is a good electron acceptor in an electron transfer reaction is going to be the element that is going to hog the electrons in a covalent bond.

    同样的,这个元素在一个电子转移反应中,是个很好的受赠者它将成为在共价电子,中吸引电子的元素。

    麻省理工公开课 - 固态化学导论课程节选

  • Not only did we figure out a way to describe how we quantify it, but we've also quantified how we tell the difference between covalent and ionic, and percent ionic character.

    我们不仅想出了一个办法来描述,我们如何定量它,而且我们也定义,我们如何分辨共价性和离子性,以及离子百分数。

    麻省理工公开课 - 固态化学导论课程节选

  • And when we talk about covalent bonds, there's 2 properties that we'll mostly focus on, and that's going to be thinking about the bond strength or the energy by which it stabilized when it bonds.

    而当我们讨论共价键的时候,有两点特性是我们最关注的,那就是键的强度,或者说成键之后能量降低了多少。

    麻省理工公开课 - 化学原理课程节选

  • So, we see is when we use the octet rule to look at fluorine molecule, we're combining two fluorine atoms, and what we end up with is an f f molecule where they're sharing two electrons, so making that covalent bond.

    那么,我们看到把八隅体规则用到氟分子上,就是把两个氟原子组合起来,最终得到的氟分子中两个原子,共用一对电子,这就构成了共价键。

    麻省理工公开课 - 化学原理课程节选

  • He introduced the concept of electronegativity which was a measure, therefore, it is quantitative, of the atom's ability to attract electrons within a covalent bond and developed a scale of electronegativity.

    他引入了电负性这一概念,一个反映着原子在成共价键时吸引电子的能力的数据标度,因此这是数量上的,在共价电子中,电子原子能吸引电子,并发展为一定规模的电负性。

    麻省理工公开课 - 固态化学导论课程节选

  • OK, he also, let me see, he also, lastly, to close us out, he also developed an analytical expression for the energy of that covalent bond, which is really what we want.

    好的,他也,让我看看,他也,最终接近我们的,他也发明了一种分析方式,对于共价键能量来说,这是我们真正想要的。

    麻省理工公开课 - 固态化学导论课程节选

  • So specifically, today we're going to talk about covalent bonds.

    特别地,今天我们要专门讲一讲共价键。

    麻省理工公开课 - 化学原理课程节选

  • Well, with covalent bonding, it's not so simple.

    但对于共价键就没这么简单了。

    麻省理工公开课 - 固态化学导论课程节选

  • Now, usually this is a non-covalent interaction.

    这通常是一种非共价化合反应

    耶鲁公开课 - 生物医学工程探索课程节选

  • So, somewhere in between, the bonds are, we have a range of bonds between ionic on the one hand, and perfectly covalent on the other hand.

    因此在中间,这些键,一方面是离子性,另一方面是完美的共价键。

    麻省理工公开课 - 固态化学导论课程节选

  • The ability of an atom to attract electrons, and in particular, in a covalent bond.

    原子对电子的吸引能力,特别是在共价键中。

    麻省理工公开课 - 固态化学导论课程节选

  • And so Pauling went further and said this is the purely covalent component.

    然后鲍林更进一步,说这是一个完全的共价成分。

    麻省理工公开课 - 固态化学导论课程节选

  • And the key word for covalent bonds is the idea of being shared.

    而关于共价键最关键的一点就在于共用的概念。

    麻省理工公开课 - 化学原理课程节选

  • This should make sense because if something has a low ionization energy, that means it's not very electronegative, which means it's going to be a lot happier giving up electron density, which is essentially what you're doing -- when you're forming covalent bonds is you're sharing some of your electron density.

    这应该是合理的,因为如果某物的电离能很低,这也就意味着它的电负性也不高,那么它就会更愿意,放弃一定的电子密度,而本质上这正是你在,形成共价键时所需要做的,分享你的一些电子密度。

    麻省理工公开课 - 化学原理课程节选

  • They say homonuclear. So this is purely covalent.

    而是用的同核,嗯,这是完全共价的。

    麻省理工公开课 - 固态化学导论课程节选

  • And he coined the term covalent bonding.

    他创造了共价键这一概念。

    麻省理工公开课 - 固态化学导论课程节选

  • So, if we look at this graph where what we're charting is the internuclear distance, so the distance between these two hydrogen atoms, as a function of energy, -- what we are going to see is a curve that looks like this -- this is the general curve that you'll see for any covalent bond, and we'll explain where that comes from in a minute.

    因此,如果我们来看一看这幅曲线图,这里我们画的横坐标是核间距,也就是这两个氢原子之间的距离,纵坐标是能量,我们看到的这是能量关于核间距的曲线-,这是一条普遍的曲线,在研究任何共价键时你都会遇到,我们马上就会解释一下它是怎么来的。

    麻省理工公开课 - 化学原理课程节选

  • We're going to talk about this kind of non-covalent interaction more when we talk about the immune system, because one example of ligand and receptors that's important in the immune system are antigens - foreign molecules, and antibodies - molecules that we produce.

    当我们讲到免疫系统的时候,会更详细地谈到这种非共价化合反应,因为在免疫系统中,一个重要的配体受体结合反应,就是抗原,即外源分子,与抗体,这个人体自身产生的分子结合

    耶鲁公开课 - 生物医学工程探索课程节选

  • Well, if it is a good electron donor in an electron transfer reaction, if the same element finds itself in a covalent bond, it is going to be a good electron donor, although it is not full transfer.

    如果它是一个在电子反应中,的好捐赠者,如果相同电子发现他在共价电子里,它将成为一个好的捐赠者,虽然没有完全转换。

    麻省理工公开课 - 固态化学导论课程节选

  • So as we said when we first introduced covalent bonds, it's a sharing of electrons, but it's not always an equal sharing.

    当我们刚开始介绍共价键的时候,我们说过电子是被共用的,但是共用却不一定是均等的。

    麻省理工公开课 - 化学原理课程节选

  • So, that's basically the idea of how we are going to be thinking about covalent bonds.

    那么,这就是我们所应该想到的基本思路,在考虑共价键时。

    麻省理工公开课 - 化学原理课程节选

  • So, in fact, yes, we did confirm that these covalent bond, at least in the case of hydrogen, we have confirmed by the numbers that we are at a lower energy state when we talk about the bonded atom versus the individual atom.

    因此,事实上,是的,我们证实了共价键,至少在氢这种情况下,我们通过数据证实了,成键的原子处于能量更低的状态,当其与单个的原子相对比时。

    麻省理工公开课 - 化学原理课程节选

  • So, in talking about covalent bonds, we should be able to still apply a more general definition of a chemical bond, which should tell us that the h 2 molecule is going to be lower in energy than if we looked at 2 separate hydrogen atom molecules.

    那么,既然提到了共价键,我们应该还可以,给化学键下一个更普遍的定义,那就是告诉我们氢分子能量应该更低,与两个分开的氢的单原子分子相比。

    麻省理工公开课 - 化学原理课程节选

  • That is what gets crunched down to covalent bonding.

    这就要归结与共价键。

    麻省理工公开课 - 固态化学导论课程节选

  • This is purely covalent because all it is is homonuclear bond energies.

    是一个完全的共价成分,他的理由是他们都是同核共价。

    麻省理工公开课 - 固态化学导论课程节选

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