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And, in fact, if any electron comes in their midst, they'll capture it because the binding energy is so high.
事实上，如果电子从中间进来，它们会捕获它,因为束缚能是如此之大。
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So when you operate on the wave function, what you end up with is getting the binding energy of the electron, and the wave function back out.
所以当你将它作用于波函数时，你得到的是电子的结合能,和后面的波函数。
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What is the binding energy of the ground state electron in hydrogen?
氢在基态的情况下,它的电子结合能是多少？
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We're going to be looking at the solutions to the Schrodinger equation for a hydrogen atom, and specifically we'll be looking at the binding energy of the electron to the nucleus.
我们将研究下氢原子薛定谔方程的解,特别是电子和核子的结合能,我们将研究这部分。
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So, what we can do is figure out what we would expect the binding energy of that electron to be in the case of this total shielding.
完全屏蔽的案例中,期望的电子结合,能再次记住,结合能物理上来说是。
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And we can look at precisely why that is by looking at the equations for the energy levels for a hydrogen atom versus the multi-electron atom. So, for a hydrogen atom, and actually for any one electron atom at all, this is our energy or our binding energy.
而且我们可以精确地看看,为什么是这样的,通过看对于氢原子和,多电子原子能级的方程所以对于氢原子，事实上对于任何一个电子，这是我们的能量或者我们的结合能。
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We've got a lot of constants in this solution to the hydrogen atom, and we know what most of these mean. But remember that this whole term in green here is what is going to be equal to that binding energy between the nucleus of a hydrogen atom and the electron.
在这个解中有很多常数,其中大部分我们,都知道它们代表的意思,但记住是这整个绿色的部分,等于核子和电子的结合能。
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So you don't want to put in a negative energy, that's not going to help you out, you need to put in positive energy to get an electron out of the system. So that's why you'll find binding energies are always negative, and ionization energies are always going to be positive, or you could look at the equation and see it from there as well.
因为这对电离没有帮助,你需要一个正的能量,使得电子脱离这个系统,这就是为什么你会发现,结合能总是负的而电离能总是正的,或者你们看这个方程也可以发现这一点。
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And we know that n describes the total energy, that total binding energy of the electron, so the total energy is going to be equal to potential energy plus kinetic energy.
我们知道，n是描述总能量的，电子总的结合能，所以总能量，等于,势能加动能。
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This e term here is the energy, or in our case when we talk about an electron in a hydrogen atom, for example, the binding energy of that electron to the nucleus.
这里的“E“是指能量，或者在我们谈论一个,氢原子的电子时，举例来说，是电子对于原子核的结合能。
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So we have the operationon the wave function in terms of r, theta, and phi and remember this e is just our binding energy for the electron, and we get back out this wave function.
我们用r，θ，φ来表示,将算符作用于波函数,而且记住e仅仅是电子结合能，然后后面加上波函数。
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We're going to get to more complicated atoms eventually where we're going to have more than one electron in it, but when we're talking about a single electron atom, we know that the binding energy is equal to the negative of the Rydberg constant over n squared, so it's only depends on n.
我们以后会讲到，更加复杂的情况,那时候,不只有一个原子，但当我们讲，单个原子的时候，我们知道结合能，等于,负的Rydberg常数,除以n平方，所以它仅仅由n决定的。
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And what we say when we talk about the delta energy is I E 2 that this is going to be equal to i e 2, or the second ionization energy, or we could say the negative of the binding energy of a 2 s electron in b plus.
那么我们说,Δ，E，应该等于，或者说第二电离能，也就是正一价硼中，2，s，电子的,束缚能的负值。
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