The whole thing's going to come to some new equilibrium temperature between the products and the oil or whatever's around it, and we're going to measure that.
生成物和周围的油或,别的什么东西之间,达到某种新的平衡态,我们要测量的就是这个。
There's our condition for equilibrium at constant temperature and pressure.
这就是我们在,恒定温度和压强下的平衡条件。
You could take a continuous path, where you have an infinite equilibrium points in between the two, a smooth path, whereyoudrop pressureand temperature simultaneosly in little increments.
你可以选择光滑的连续路径,在初末态间有,无数个平衡态的点,压强和温度同时一点,一点地下降。
And the triple point of water is 16K that temperature and pressure - there's a unique temperature and pressure where water exists in equilibrium between the liquid phase, the vapor phase, and the solid phase.
与水的三相点,我们定义它为273。,水的三相点,是一个特定的温度和压强,可以使水的液态,气态和固态三相共同达到平衡,三相点是液态。
If I look at different points in my container during that path, I'm going to have to use a different value of pressure or different value of temperature That's not an equilibrium state, and that process turns out then to be an irreversible process.
如果我要研究在路径中容器里的,不同的点,我就得在容器里不同的点上使用,不同的压强值,或不同的温度值,实际上这不是个平衡态,这个过程是,不可逆过程。
pV Also A plus pV and G is minimized at equilibrium with constant temperature and pressure.
同时等于亥姆赫兹自由能A加上,同时在恒定的温度和压强下。
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