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Water is made of one oxygen atom and two hydrogen atoms.
VOA: special.2009.09.30
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Let's look at the energetics of one of those electrons crashing into a hydrogen atom inside the gas tube.
我们一起来考察一下,其中的一个电子的能量,在阴极射线管中,撞击到氢原子上。
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So if I tell you that the energy for single hydrogen atom is negative 13 12 kilojoules per mole.
如果我告诉大家单个氢原子的能量,是负的，1312，千焦每摩尔。
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That energy will be absorbed by the hydrogen atom, n=1 the electron will rise from n equals one n=2 to n equals two.
这能量将会被氢原子吸收，这个电子会从,上升到。
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So, what we get for the disassociation energy for a hydrogen atom is 424 kilojoules per mole.
因此，我们就得到了氢原子,离解能的大小为，424，千焦每摩尔。
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One of the main difference is is that when you're talking about multi-electron orbitals, they're actually smaller than the corresponding orbital for the hydrogen atom.
其中最主要的区别之一,是当你讨论多电子轨道时,它们实际上，要比对应的氢原子轨道,要小一些。
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Also, when we're looking at the Schrodinger equation, it allows us to explain a stable hydrogen atom, which is something that classical mechanics did not allow us to do.
当我们看一个薛定谔方程的时候，它给出一个稳定的氢原子,这是在经典力学中做不到的。
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Here we're talking about a hydrogen atom and that's what we'll focus on today. And it's incredibly precise and we're able to make the predictions and match them with experiment.
是一个氢原子，我们今天都主要讨论它,它非常准确，我们可以做出,预测与实验比较，此外。
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So if we're talking about the fourth excited state, and we talk instead about principle quantum numbers, what principle quantum number corresponds to the fourth excited state of a hydrogen atom.
如果我们说的是,第四激发态，我们用,主量子数来描述，哪个主量子数对应了,氢原子的第四激发态？
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And I just want to point out here in terms of things that you're responsible for, you should know that the most probable radius for a 1 s hydrogen atom is equal a nought.
在这里,我想要指出的是，你们要知道氢原子１ｓ轨道,最可能距离等于ａ０
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So, for example, in a hydrogen atom, if you take the binding energy, the negative of that is going to be how much energy you have to put in to ionize the hydrogen atom.
例如在氢原子里面,如果你取一个结合能,它的负数就是。
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It turns out, and we're going to get the idea of shielding, so it's not going to actually +18 feel that full plus 18, but it'll feel a whole lot more than it will just feel in terms of a hydrogen atom where we only have a nuclear charge of one.
结果是我们会有,屏蔽的想法,所以它不会是完整的，但是它会比原子核电荷量,吸引力要大很多,只有1的氢原子的。
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Because what it tells is that we can figure out exactly what the radius of an electron and a nucleus are in a hydrogen atom.
我们可以,准确的算出,氢原子中,电子。
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All right. So, let's pick up where we left off, first of all we're still on the hydrogen atom from Monday.
好，让我们从上次停下的地方讲起，我们还要讲周一讲的氢原子。
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a0 This is equal to a sub nought for a hydrogen atom, and we remember that that's just our Bohr radius, which is . 5 2 9 angstroms.
它等于,我们记得，这就是波尔半径,也就是0，529埃，实际上。
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We're going to be looking at the solutions to the Schrodinger equation for a hydrogen atom, and specifically we'll be looking at the binding energy of the electron to the nucleus.
我们将研究下氢原子薛定谔方程的解,特别是电子和核子的结合能,我们将研究这部分。
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In terms of where different atoms are in a molecule, if you have a hydrogen atom or a fluorine atom, you can pretty much guarantee they're always going to be terminal atoms.
对于不同原子在分子中的位置，如果你有一个氢原子或者一个氟原子，那你基本可以保证,它们总是最末端的原子。
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And even though he could figure out that this wasn't possible, he still used this as a starting point, and what he did know was that these energy levels that were within hydrogen atom were quantized.
这是不可能的了,但他还是以此为出发点，他知道，氢原子的这些能级,是量子化的,而且他也知道，我们上节课所看到现象。
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If we want to talk about two hydrogen atoms, then we just need to double that, so that's going to be negative 2 6 2 4 kilojoules per mole that we're talking about in terms of a single hydrogen atom.
而要讨论两个氢原子，我们只需要把它乘以二，因此应该是负的，2624，千焦每摩尔,这就是单个的氢原子的情况。
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But, in fact, we can also talk about the ionization energy of different states of the hydrogen atom or of any atom.
但实际上我们也可以讨论氢原子,或者其它任何原子的其它能级的电离能。
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If we know that this is it the dissociation energy for a hydrogen atom, we can also say the bond strength for hydrogen molecule 424 is 424.
如果我们知道了这是一个氢分子的离解能,那么我们也可以说氢分子的键的强度,就是。
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So, what we know is happening is that were having transitions from some excited states to a more relaxed lower, more stable state in the hydrogen atom.
我们知道，这里所发生的是,氢原子从激发态到更低更稳定的态的跃迁，而我们用眼睛可以探测到的。
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And it should make sense where we got this from, because we know that the binding energy, if we're talking about a hydrogen atom, what is the binding energy equal to?
很容易理解，我们怎么得到这个的，因为我们知道，结合能，如果，对氢原子来说，结合能等于什么？
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And what is discussed is that for a 1 s hydrogen atom, that falls at an a nought distance away from the nucleus.
我们讨论了对于氢原子１ｓ轨道，它的最可能半径在距离原子核ａ０处。
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So let's compare what some of the similarities and differences are between hydrogen atom orbitals, which we spent a lot of time studying, and now these one electron orbital approximations for these multi-electron atoms.
很长时间的氢原子轨道和,现在多电子原子中,的单个电子轨道近似，我们可以对比，它们之间,的相似性和不同。
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So, I'm asking very specifically about radial nodes here, how many radial nodes does a hydrogen atom 3 d orbital have?
我问的是径向节点，这里3d轨道的径向节点有多少个？
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All right. So today we're going to finish up our discussion of the hydrogen atom.
好，今天我们要结束,关于氢原子问题的讨论。
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And there again is another difference between multi-electron atom and the hydrogen atoms.
在多电子原子和氢原子,之间还有一个区别,当我们谈论多电子原子轨道时。
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So, what this lets us do now is directly compare, for example, the strength of a bond in terms of a hydrogen atom and hydrogen molecule, compared to any kind of molecule that we want to graph on top of it.
因此，这让我们现在可以做到直接进行比较，比如，将一个氢原子，和一个氢分子的键的强度，与任何其它类型的分子进行比较,我们只需要把它的曲线也画在这幅图上。
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So again, what we're saying here is that it is most likely in the 3 s orbital that we would find the electron 11 and 1/2 times further away from the nucleus than we would in a around state hydrogen atom.
同样我们,这里说的是,氢原子３ｓ轨道中,最可能找到电子的地方,是基态的１１．５倍。
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