And if you work out the energetics as we've gone with thermochemistry, dH you discover there's a huge negative delta H.
如果你计算能量变化,就像在化学热力学中所作的一样,你会发现很大的负的。
Delta v is positive in this direction here, the work is negative. So work on the system is positive. Work done by the system is negative.
功是负的,总而言之,外界对系统做功的符号为正。
And so, in fact, the delta here is negative.
因此,实际上这里的delta,E是负的。
So delta u of reaction is approximately equal T to negative Cv for the calorimeter times delta T.
所以反应的ΔU近似等于,负的量热计的Cv乘以Δ
So if delta v is negative, in this case delta v is negative, OK, delta v is negative, pressure is a positive number, negative times negative is positive, work is greater than zero.
也就是当活塞,压缩气体的时候,做的功是正的,按照这一规定,我们需要在这里,加上一个负号,这是习惯规定。
Delta v is going to be negative. w is going to be negative. Sorry, I got it backwards again.
这样就对外界做了功,这时候ΔV是正的。
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