And the significant difference between s orbitals and p orbitals that comes from the fact that we do have angular momentum here in these p orbitals, is that p orbital wave functions do, in fact, have theta and phi dependence.

轨道和ｐ轨道的,不同之处在于,在ｐ轨道，波函数，随theta和phi变化。

麻省理工公开课 - 化学原理课程节选

In contrast when we're looking at a p orbital, so any time l is equal to 1, and you look at angular part of the wave function here, what you see is the wave function either depends on theta or is dependent on both theta and phi.

相反当我们看ｐ轨道时，任何时候ｌ等于１,你们看它的角向波函数，你们可以看到它要么是和theta有关,要么是和theta和phi都有关。

麻省理工公开课 - 化学原理课程节选

So they're the same shape, this is the shape of the orbital or the shape of the wave function, and we can call this either 2 p x a being combined with 2 p x b, or we could say since it's the same shape, it's 2 p y a being combined with 2 p y b.

它们形状是一样的，这是轨道的形状或者波函数的形状，我们叫它2pxa和2pxb结合，或者我们说因为它们的形状是一样的，它是2pya和2pyb结合。

麻省理工公开课 - 化学原理课程节选

pxa So what happens when we add a 2 p a and we subtract from it a 2 p x b, or the same with a 2 p y a subtracting a 2 p y b, is that we're actually going to cancel out the wave function in the center, so we now have 2 nodal planes.

当我们用,减去2pxb时，或者是2pya减去2pyb时，我们会消去,中间的波函数，所以现在我们有两个节面。

麻省理工公开课 - 化学原理课程节选