Whereas under these conditions, these quantities, if you look at free energy change, for example at constant temperature and pressure, H you can still calculate H.
但是,在这些条件下,这些物理量,如果我们考察自由能的变化,例如在恒定的温度和压强下,我们仍然可以计算。
You just change volume to pressure and basically you're looking at enthalpy under a constant -- anything that's done at a constant volume path with energy, there's the same thing happening under constant pressure path for enthalpy.
可以看到这就是把体积换成了压强,一般我们都是在一种恒定状态下,考虑焓的,任何在恒容条件下,能伴随能量变化的东西,也在恒压条件下伴随焓同样地变化,所以你可以经常。
If we have too much gas in here, in other words, if the gas is at too high a pressure, the collisions with the gas molecules will consume the energy of the electrons and, again, we will see nothing.
假设这里有过多气体,换句话说,如果气体处在一个高压状态下,气体分子间的碰撞将会消耗,电子的能量,同样,什么也没有。
So you can imagine that adds real excitement and energy to the class and puts a little bit pressure on the professors to make sure that we have something worth coming half way around the world for.
可以想象,为课堂带去的兴奋和活力,也给教授施加了压力,我们要确保,能传授值得绕半个地球赶来学习的知识。
So again with the Gibbs free energy, now I see how to determine, if I change the pressure, if I change the temperature by some modest amount, how much is the Gibbs free energy going to change?
再一次通过吉布斯自由能,我知道当我,适当的改变压强和,温度的时候,吉布斯自由能如何变化?
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