px So we're talking about pi carbon 2 p x, 2px because it's the x axes combining to carbon 2 p x.
我们讨论的是π碳,因为它在x轴结合成碳。
px 2py So we need to fill all the way up to the pi 2 p x, and the pi 2 p y.
我们需要填到。
px We'll call it either pi 2 p x, 2py if we're combining the x orbitals, or pi 2 p y.
我们叫它π,如果是x轨道组合的话,或者π
px And I arbitrarily chose to put it in the 2 p x, 2pz we also could have put it in the 2 p y or the 2 p z, it doesn't matter where you double up, they're all the same energy.
我任意地选择放入至,我们也可以把它放入2py或,它与你在哪双倍填充没有关系,它们都在相同的能级。
And the pi star orbitals result from any time you have destructive py interference from 2 p orbitals that are either the p x or the p y.
星轨道是由于2p轨道的相消干涉,不管是px还是。
1 Similarly, if m is equal to either plus 1 or minus 1, py we would in turn call it the p y orbital, or the p x orbital.
类似的,如果m等于+1或,我们可以叫它,或者px轨道。
So it's OK to not specify. I want to point out, pz whether you're in the p x, the p y, or the p z, unless a question specifically m asks you to specify the m sub l, which occasionally will happen, but if it doesn't happen you just write it like this.
我想指出的是,无论你在px,py或,除非一个问题特别地,让你指出l下面的,这种情况有时会发生,这样就可以了,但是如果它不做要求你们写成。
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