What was neat about it is before that time, the predominant species to use for air conditioning or refrigeration was ammonia.
在这之前是很整洁的,之前最主要的用于空调或者冰箱的,物质是氨。
And, not too many people, actually, if you talk to your grandmother or grandfather, there were some refrigerators that were actually made that used ammonia.
但是,并非太多的人,如果你会对你的祖父,祖母谈谈,或许有一些冰箱,实际上是用氨。
Let's just take hydrogen and nitrogen in the gas phase and form ammonia.
我们利用氢气和氮气,合成氨。
So what we see is on ammonia here, 107 we know that it's less than a 109 . 5, it's actually 107, so it's less than a 109 . 5, because of that lone pair pushing down in the bonding electrons.
我们看到在氨分子里,我们知道它比109.5要小,它是,所以比109。5要小,因为孤对会把成键电子向下推。
And what is the shape, for one more clicker question on ammonia?
那它的形状呢?,再来一道关于氨分子的课堂习题?
He invented ammonia synthesis with catalysis by iron.
它发现了铁催化合成氨的催化反应。
So we can have our two hydrogen atoms come in here, and what we will find is - now that we have all of our orbitals filled up -- so thinking about what this angle is here, would you expect it to be less than or greater than what we saw for ammonia before?
我们在这里有两个氢原子,我们会发现,现在我们所有的轨道都填满了-,考虑一下这里的角度,你们觉得它比在氨中看到的,要大还是要小?
So if we do this and we form the molecule ammonia, let's switch to a clicker question, and have you tell me what the bond angle - is going to be in ammonia -- HNH Actually, let me draw it on the board as you look -- actually, can you put the class notes on, since you don't actually have your notes to refer to.
如果这样做的话,我们就可以形成氨分子,让我们来做一个课堂练习,你们告诉我氨分子中的键角是多少-,键角,the,h,n,h,bond,angle。,实际上让我在黑板上画出它来,这样你们可以看到实际上-,你能把课堂讲义放出来吗,因为你们没有讲义可以参考。
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