• Bohr expressed the quantum condition by the angular momentum, quantum condition in the following manner.

    波尔阐明了他的量子理条件,通过角动量,和以下的量子条件进行量子化。

    麻省理工公开课 - 固态化学导论课程节选

  • Bohr said that the angular momentum, mvr where n is this integer counter h over 2 pi.

    波尔提及到角动量,是被量化了的,mvr,is,quantized,这里的n等于一个整数乘以h除以2π

    麻省理工公开课 - 固态化学导论课程节选

  • It describes the angular momentum of the electron.

    它描述的是,电子的叫角动量。

    麻省理工公开课 - 化学原理课程节选

  • Bohr says that the energy is quantized through its angular momentum.

    波尔说能量通过角动量,被量子化。

    麻省理工公开课 - 固态化学导论课程节选

  • And the first is l, and l is angular momentum quantum number, and it's called that because it dictates the angular momentum that our electron has in our atom.

    第一个就是l,l是,角动量量子数,叫它这个名字,是因为它表明,原子中,电子的角动量是多少。

    麻省理工公开课 - 化学原理课程节选

  • So since it's a component of the angular momentum, that means that it's never going to be able to go higher than l is, so it makes sense that, for example, it could start at and then l go all the way up to l.

    因为,它是,角动量的分量,这意味着,它不会,比l大,这是很容易理解的,比如说,它可以从零开始,一直到。

    麻省理工公开课 - 化学原理课程节选

  • We can actually think about why that is, and the reason is that l is angular momentum.

    我们可以这样想,因为,l是角动量。

    麻省理工公开课 - 化学原理课程节选

  • And the significant difference between s orbitals and p orbitals that comes from the fact that we do have angular momentum here in these p orbitals, is that p orbital wave functions do, in fact, have theta and phi dependence.

    轨道和p轨道的,不同之处在于,在p轨道,波函数,随theta和phi变化。

    麻省理工公开课 - 化学原理课程节选

  • The other main difference that we're really going to get to today is that in multi-electron atoms, orbital energies depend not just on the shell, which is what we saw before, not just on the value of n, but also on the angular momentum quantum l number. So they also depend on the sub-shell or l.

    我们今天要讨论的,另一个很重要的区别就是,在多电子原子中,轨道能力不仅仅依赖于,我们以前看到的外层,不仅仅依赖于n的值,而是与角动量量子数也有关系,所以它们也依赖于亚外层或者。

    麻省理工公开课 - 化学原理课程节选

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