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This cation is attracting the chloride next to it and it is repelling the sodium as the next nearest neighbor.
这一阳离子被邻近的氯离子所吸引,并排斥钠离子,因为这是其最邻近的离子。
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We talked about this reaction here where we had chloride ion in the gas phase plus sodium ion in the gas phase.
我们在讨论这一个反应,我们有气相的氯原子,与气相的钠原子接触。
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So why don't you tell me what the formal charge should be on the sulfur atom of thionyl chloride?
那么请大家来告诉我亚硫酰氯中,的硫原子应该有多少形式电荷？
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The ones that are most important in physiology are ones that only allow ions to go through: sodium, potassium, chloride, calcium, bicarbonate.
在生理学上这种,只能允许某种离子通过的通道十分重要,这些离子包括钠离子,钾离子,氯离子,钙离子和碳酸氢根离子
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We started with gaseous sodium to make gaseous sodium ion and gaseous atomic chlorine to make gaseous chloride ion through electron transfer.
我们从气态的钠开始,得到气态的钠离子,从气态的氯原子,通过电子转移得到氯离子。
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So now, let's get a sodium here, and the chloride ion next to it to the point where they are touching.
所以，我们要有一个钠离子，和氯离子放在,相互接触的一个点上。
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And so what you're going to end up with is, well, let's go over that. Here is sodium and chloride.
你将以之结尾，好吧，我们跳过那个，这是钠和氯。
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So just keep in mind when you do see the chlorine in these drugs, it's very different from the acid chloride.
因此只要记住当你在这些药物中发现氯的时候，它不会是酰氯就好了。
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If you take one of those individual grains of sodium chloride, look at it carefully, you will see the edges look like this.
如果你拿起,氯化钠晶体的一粒，仔细观察，你可以看到这样的棱角。
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And, we're going to look at what happens as the chloride ion moves from infinity in towards the positive ion.
然后我们要看一下,当氯离子从无限远处逐渐靠近,这个正离子会发生什么。
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And then, if you go the real sodium chloride crystal and you do this same calculation but in three-dimensions.
接下来，如果回到实际的氯化钠晶体中,你们做同样的计算,但是是在三维中。
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And I want that to react to give me sodium chloride as a solid and crystal.
它们反应会得到氯化钠,氯化钠固体晶体。
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So, which atom would you expect to be in the center of a Lewis structure for thionyl chloride?
那么，大家认为那个原子应该在,亚硫酰氯的路易斯结构的中心位置呢？
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And I know that sodium chloride forms because, if I look on the webpage at 3.091, you see this down here, this is sodium in kerosene.
我知道氯化钠形式，因为我看过3。091的网站，看看这个，这是钠在煤油中。
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And what it's used is to convert one type of group, what's called a carboxylic acid into another type of very reactive intermediate, which is called an acid chloride.
它被用来将一类被称作羧酸的化合物，转化成另外一类活性很高的反应中间体,也就是酰氯。
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Magnesium chloride is the raw material for the production of magnesium.
氯化镁是一种由镁得到的,天然材料。
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actually our third, but the second one we're going to talk about in terms of formal charge, which is thionyl chloride.
实际上是第三个，但它是第二个,形式电荷的例子，也就是亚硫酰氯。
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So again, we should be able to check all of our formal charges and make sure they add up to 0, which they do, and that makes sense, because we have a neutral atom in terms of thionyl chloride.
因此同样地，我们可以检验一下,我们所有的形式电荷是否正确,确保它们加起来等于零，而它们确实是这样，这是合理的，因为亚硫酰氯是一个中性原子。
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And so you can imagine that if you mix these, if you take sodium and you mix it with chlorine you get sodium chloride.
如果将它们混合，以钠和氯反应为例,就会反应得到氯化钠。
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Well, if we just take, for example, MgO, and let's try Mg, magnesium chloride just as an example.
我们以MgO为例，让我们试试Mg，MgCl2也是一个例。
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It still has positive charge, and there is nothing saying another chloride could not stick to it.
它仍然具有正电荷，不能说明另外一个氯,不能固定在上面。
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Electrolysis of magnesium chloride in a cell where the one electrode we would make magnesium.
在电池内电解氯化镁,我们能在其中一个电极上得到镁。
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And you will form a crystal of sodium chloride as a result of this need to form crystal expressed through the Coulomb's Law.
你能得到氯化钠晶体,因此，形成晶体所需要的条件,在库伦定律中通篇都有表达。
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I know table salt is white, but that is because you have power and you have multiple surfaces scattering, but a large crystal of sodium chloride is clear and colorless.
我知道食用盐是白色的，但这是因为你让它成了粉末,因为有了多个散射面，但是一个大的氯化钠晶体,是无色透明的。
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A sodium chloride crystal is transparent to visible light.
氯化钠晶体对可见光透明。
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And there is this separation which is a balance of attractive forces because the chloride is net negative and the sodium is net positive, but both of them, regardless of net charge, have electrons.
这里有一个平衡,引力的平衡,由于氯离子带有负的净电荷,钠离子带有正的净电荷，但是它们两个，没有考虑净电荷，电子。
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And the last example that we're going to talk about is thionyl chloride, so it's s o c l 2. This is another good step forward, because now we actually have four different atoms in our molecule.
我们要讨论的最后一个例子,是氯化亚砜，就是硫，氧，氯，二，这又是一个进步，因为我们的分子中现在有四个不同的原子了。
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So I show that here, so in green, you have what's called a carboxcylic acid group, a c o o h, which gets converted by s o c l 2 to a c double bond o c l or an acid chloride.
我在这里用绿色表示，我们所说的羧酸族化合物，碳，氧，氧，氢，它被亚硫酰氯转化为,一个碳氧双键与碳氯单键组成的酰氯。
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We see that we get a negative energy by attaching the chloride to the sodium.
我们得到了负能量,通过将氯和钠结合在一起。
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