He said that the percent ionic character, and this is within a bond, not for a compound, for a covalent bond.
他提到离子百分数,是指一根键中,并非一个分子中。
CO Right, so you take the co here, and we take the valence here, and out of that comes covalent.
好了,然后我们看到,我们可以看到他的化合价,他们成共价键。
A covalent bond is any time we have a pair of electrons that is shared between two different atoms.
所谓共价键就是我们有两个原子,共用一对电子。
There's not actually chemical covalent bonds that are formed but it's a non-covalent interaction, usually dominated by hydrogen bonding.
所以配体和受体之间不生成共价键,这是一种非共价化合反应,它们通常以氢键相联
OK, so what we've gone through today is we've introduced covalent bonding, and we've figured out a way to quantify it.
好的,那么我们已经经历了,是我们已经介绍了共价键,我们已经想出了一种定量的方法来。
Likewise, the element that is a good electron acceptor in an electron transfer reaction is going to be the element that is going to hog the electrons in a covalent bond.
同样的,这个元素在一个电子转移反应中,是个很好的受赠者它将成为在共价电子,中吸引电子的元素。
Not only did we figure out a way to describe how we quantify it, but we've also quantified how we tell the difference between covalent and ionic, and percent ionic character.
我们不仅想出了一个办法来描述,我们如何定量它,而且我们也定义,我们如何分辨共价性和离子性,以及离子百分数。
And when we talk about covalent bonds, there's 2 properties that we'll mostly focus on, and that's going to be thinking about the bond strength or the energy by which it stabilized when it bonds.
而当我们讨论共价键的时候,有两点特性是我们最关注的,那就是键的强度,或者说成键之后能量降低了多少。
So, we see is when we use the octet rule to look at fluorine molecule, we're combining two fluorine atoms, and what we end up with is an f f molecule where they're sharing two electrons, so making that covalent bond.
那么,我们看到把八隅体规则用到氟分子上,就是把两个氟原子组合起来,最终得到的氟分子中两个原子,共用一对电子,这就构成了共价键。
He introduced the concept of electronegativity which was a measure, therefore, it is quantitative, of the atom's ability to attract electrons within a covalent bond and developed a scale of electronegativity.
他引入了电负性这一概念,一个反映着原子在成共价键时吸引电子的能力的数据标度,因此这是数量上的,在共价电子中,电子原子能吸引电子,并发展为一定规模的电负性。
OK, he also, let me see, he also, lastly, to close us out, he also developed an analytical expression for the energy of that covalent bond, which is really what we want.
好的,他也,让我看看,他也,最终接近我们的,他也发明了一种分析方式,对于共价键能量来说,这是我们真正想要的。
So specifically, today we're going to talk about covalent bonds.
特别地,今天我们要专门讲一讲共价键。
Well, with covalent bonding, it's not so simple.
但对于共价键就没这么简单了。
Now, usually this is a non-covalent interaction.
这通常是一种非共价化合反应
So, somewhere in between, the bonds are, we have a range of bonds between ionic on the one hand, and perfectly covalent on the other hand.
因此在中间,这些键,一方面是离子性,另一方面是完美的共价键。
The ability of an atom to attract electrons, and in particular, in a covalent bond.
原子对电子的吸引能力,特别是在共价键中。
And so Pauling went further and said this is the purely covalent component.
然后鲍林更进一步,说这是一个完全的共价成分。
And the key word for covalent bonds is the idea of being shared.
而关于共价键最关键的一点就在于共用的概念。
This should make sense because if something has a low ionization energy, that means it's not very electronegative, which means it's going to be a lot happier giving up electron density, which is essentially what you're doing -- when you're forming covalent bonds is you're sharing some of your electron density.
这应该是合理的,因为如果某物的电离能很低,这也就意味着它的电负性也不高,那么它就会更愿意,放弃一定的电子密度,而本质上这正是你在,形成共价键时所需要做的,分享你的一些电子密度。
They say homonuclear. So this is purely covalent.
而是用的同核,嗯,这是完全共价的。
And he coined the term covalent bonding.
他创造了共价键这一概念。
So, if we look at this graph where what we're charting is the internuclear distance, so the distance between these two hydrogen atoms, as a function of energy, -- what we are going to see is a curve that looks like this -- this is the general curve that you'll see for any covalent bond, and we'll explain where that comes from in a minute.
因此,如果我们来看一看这幅曲线图,这里我们画的横坐标是核间距,也就是这两个氢原子之间的距离,纵坐标是能量,我们看到的这是能量关于核间距的曲线-,这是一条普遍的曲线,在研究任何共价键时你都会遇到,我们马上就会解释一下它是怎么来的。
We're going to talk about this kind of non-covalent interaction more when we talk about the immune system, because one example of ligand and receptors that's important in the immune system are antigens - foreign molecules, and antibodies - molecules that we produce.
当我们讲到免疫系统的时候,会更详细地谈到这种非共价化合反应,因为在免疫系统中,一个重要的配体受体结合反应,就是抗原,即外源分子,与抗体,这个人体自身产生的分子结合
Well, if it is a good electron donor in an electron transfer reaction, if the same element finds itself in a covalent bond, it is going to be a good electron donor, although it is not full transfer.
如果它是一个在电子反应中,的好捐赠者,如果相同电子发现他在共价电子里,它将成为一个好的捐赠者,虽然没有完全转换。
So as we said when we first introduced covalent bonds, it's a sharing of electrons, but it's not always an equal sharing.
当我们刚开始介绍共价键的时候,我们说过电子是被共用的,但是共用却不一定是均等的。
So, that's basically the idea of how we are going to be thinking about covalent bonds.
那么,这就是我们所应该想到的基本思路,在考虑共价键时。
So, in fact, yes, we did confirm that these covalent bond, at least in the case of hydrogen, we have confirmed by the numbers that we are at a lower energy state when we talk about the bonded atom versus the individual atom.
因此,事实上,是的,我们证实了共价键,至少在氢这种情况下,我们通过数据证实了,成键的原子处于能量更低的状态,当其与单个的原子相对比时。
So, in talking about covalent bonds, we should be able to still apply a more general definition of a chemical bond, which should tell us that the h 2 molecule is going to be lower in energy than if we looked at 2 separate hydrogen atom molecules.
那么,既然提到了共价键,我们应该还可以,给化学键下一个更普遍的定义,那就是告诉我们氢分子能量应该更低,与两个分开的氢的单原子分子相比。
That is what gets crunched down to covalent bonding.
这就要归结与共价键。
This is purely covalent because all it is is homonuclear bond energies.
是一个完全的共价成分,他的理由是他们都是同核共价。
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