And so that led us to the definitions of other energy quantities, the Helmholtz and Gibbs free energy.
这就要求我们定义,其他的和能量相似的物理量,亥姆赫兹和吉布斯自由能。
The Gibbs free energy. Notice, we could also write, let's rewrite that.
吉布斯自由能,注意,我们还可以这样写,重写一下。
So again with the Gibbs free energy, now I see how to determine, if I change the pressure, if I change the temperature by some modest amount, how much is the Gibbs free energy going to change?
再一次通过吉布斯自由能,我知道当我,适当的改变压强和,温度的时候,吉布斯自由能如何变化?
It's the state that has the lowest Gibbs free energy.
它具有最小的吉布斯自由能。
Where the Gibbs free energy, TS u plus pV minus TS is H minus TS.
吉布斯自由能等于,内能u加上pV减去TS,也是自由焓H减去。
And that's why the Gibbs free energy is just so enormously important.
吉布斯自由能G在平衡态取得最小值,吉布斯自由能是最重要的。
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