So now I've got this gamma placed in there, -1 gamma minus 1, so I've ben feeling a little bit better.
这样我把这里的指数,换成γ,这样看起来舒服一些。
So now if I look at my V1 over V2 to the gamma minus 1, that's T2 over T1.
于是把^=中2,的两个温度。
So this delta energy here is very simply the energy of the initial state minus the energy of the final state.
很简单的,这个能量差等于,初始能量减去末能量。
475 Multiply by 1.7475 787kJ/mol and you end up with minus 787 kilojoules per mole.
乘以1。,最终得到。
So we would say the real interest rate equals the nominal rate-- approximately equals--the nominal rate minus the inflation rate.
我们可以推出实际利率约等于,名义利率减去通货膨胀率
Anything where you're actually keeping track of something like a score that's having a variable that you increment -- plus, plus, or decrement, minus, minus, using the appropriate puzzle piece could certainly be compelling.
你需要保存像分数这样的事物时,你就需要一个变量,它可以自加,++,或者自减,要使用正确的拼图。
So I'm first going to look for something that's not in the list, I'm going to see, is minus 1 in this list, so it's going to be at the far end, and if I do that in the basic case, bam.
如果我试试第一种最基本的方法,噢,一下就完成了对不对?,因为这种方法查了下第一个元素,然后发现目标数比较下,因为目标数小于第一个元素。
it's going to be: 1 minus the probability they'll choose Right times 1, plus the probability that they choose Right times 4.
方程是,1减对手选右的概率再乘以1,加上对手选右的概率乘以4
And in terms of radial nodes, we have 2 minus 1 minus 0, so what we have is one radial node.
对于径向节点,我们有2减去1减去0,所以有一个径向节点。
R/Cv OK, so that means that this is really instead of -1 R over Cv. it's really gamma minus one.
现在,变成了γ
Our ionization energy is going to be equal to the incident energy coming in, minus the kinetic energy of the electron.
我们的电离能将等于,入射能量,减去电子的动能。
That's the important message, delta H of formation of the products, minus delta H of formation of the reactants.
去反应物的生成焓,这,是个重要的信息,生成物的生成焓,减去反应物的生成焓。
And you would expect that that would be a much stabler compound because, instead of plus one attracting plus one, now you have plus two attracting minus two.
可以预见,这将会是更稳定的化合物,因为不再是一价正离子吸引一价负离子,而是二价正离子吸引二价负离子。
So, selenium 2 minus is what's going to be isoelectronic, because if you add two electrons to selenium, you'll get the same electron configuration that you have for krypton here.
负二价的硒离子将是等电子的,因为如果你给硒原子加上两个电子,你会得到,和氪原子相同的电子排布。
Square root of 16, and my plot basically shows it crosses at 4 and-- well, I think that's minus 4.
我的图清楚的显示这个函数,在4和-4两个点和x轴交合。
*10^-18 1.6 times 10 to the minus 18, excuse me, 6*10^-19 we have 1.6 times 10 to the minus 19, 2.18 times 10 to the minus 18, etc.
。,1。,2。18*10^-18,等等。
If I look for, say, minus 1, you might go, gee, wait a minute, if I was just doing linear search, I would've known right away that minus one wasn't in this list, because it's sorted and it's smaller than the first elements.
如果我要查找-1,你可能要怒了,呵呵,等一等,如果我用的是线性查找,我不会知道-1不在这个列表中,但是列表是排好序的,1又比第一个元素小。
So if you get these two guys together you get CvdT=-pdV Cv dT is minus p dV.
把它们联系,起来。
And we can calculate that with the formula that we used, which was just n minus l minus 1 equals the number of nodes.
这个我们可以用我们以前用过的那个公式来计算,也就是节点数等于n减去l减去1
All right, so the bonding order, you're correct, should be 2, if we subtract the number of bonding minus anti-bonding electrons and take that in 1/2.
好,你们是对的,键序为,如果我们用成键数,减去反键数除以2。
Remember, we don't do a one-to-one correlation, because p x and p y are some linear combination of the m plus 1 and m minus 1 orbital.
记住,我们不需要把它们一一对应,因为px和py轨道是,m等于正负1轨道的线性组合。
So kind of that strange cursive r, and our n final is 2, R so 1 over 2 squared minus n initial, so 1 over 3 squared.
因为我们可以在这里用到它,这个有点奇怪的花体。
STUDENT: PROFESSOR: Oh, I'm sorry. So it's n minus l minus 1.
学生:,教授:不好意思,这是n减去l减去1.
So, if we think about the second case here where we have c n minus, now we're talking about a molecule with a net charge of negative 1.
那么,如果我们考虑的是第二个例子,也就是氰离子,那么现在我们讨论的是一个净电荷量为负一的分子。
So we have 4 plus 5, but we're actually not done yet, because it's c n minus, so if we have minus, we actually have an extra electron in our molecule.
我们有四个加上五个,但是我们实际上还没做完,因为这是个负离子,所以如果我们有这个负号,那么我们的分子实际上还有一个额外的电子。
So, you should know that there's four radial nodes, right, we have 5 minus 1 minus l -- is there a question?
你们要记住这里有四个节点,对吧,5减去1减去l,有问题吗?
For the sulfur, we start off with 6 valence electrons, minus 4 lone pair electrons, minus 2, taking in account our bonding electrons, so we end up with a formal charge of 0.
对于硫,我们从六个价电子开始,减去四个孤对电子,再减去二,算上我们的成键电子,因此最终我们有零个形式电荷。
If we try this for the 2 s, we have 2 minus 1 minus 0.
我们有2减去1减去,所以我们可以预期看到。
It is of opposite charge and it exerts an influence, only that is minus to plus so that is going to give me a minus term here.
它具有相反的电性,所以它也会有影响,只有这个负值相对正值来说会起到减少的作用,所以这里将会引入一个负值的量。
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