If you divide the two of them through you will get 6.02 times 10 to the plus 23 per mole.
如果你除以他们两个,你会得到6。02*10^摩尔。
P dV is equal to R dT. pV = RT for 1 mole, pdV=RdT so I just take dV here.
对等压过程,那么。
So if I tell you that the energy for single hydrogen atom is negative 13 12 kilojoules per mole.
如果我告诉大家单个氢原子的能量,是负的,1312,千焦每摩尔。
It is joules per atom. Or, if you multiply by Avogadro's number then you will get joules per mole.
焦耳每个原子,或者,如果乘以,阿伏伽德罗常数你会得到焦耳数每摩尔。
So, what we get for the disassociation energy for a hydrogen atom is 424 kilojoules per mole.
因此,我们就得到了氢原子,离解能的大小为,424,千焦每摩尔。
And, likewise, if we look at fluorine in its diatomic molecule, it is 160 kilojoules per mole.
一样的,如果我们观察二价的氟,它是每摩尔160焦。
So, if I look at the mole ratios on the reaction over there I'm going to find that I'll be able to consume, at most, 1,029 over two, right?
所以,注意反应的摩尔比,我们会发现,1029摩尔的镁能被消耗,对吧?
This will be the definition of the mole as the amount of carbon weighing exactly 12 grams, so I would like to know now how many particles, how many carbons are there in that mole.
摩尔的定义就是,12克的碳的数量,我想知道有多少粒子,一摩尔会有多少碳粒子。
The volumes per mole of that stuff.
每摩尔物质的体积。
Cp, I forgot to put my little bar on top here because it's per mole Cp dT that's my dq here.
上面的Cv我忘记加上横线了,因为它也是摩尔热容。
In contrast, the dissociation energy of a bond for hydrogen, and molecular hydrogen is everywhere around us, we see 432 kilojoules per mole.
相反,氢分子在我们周围到处都是,一个氢分子的离解能,是432千焦每摩尔。
So, for example, for the chlorine case, we would say that the electron affinity for chlorine is actually positive 349 kilojoules per mole.
比如,以氯为例,我们可以说氯的电子亲和能,应该等于正的,349,千焦每摩尔。
475 Multiply by 1.7475 787kJ/mol and you end up with minus 787 kilojoules per mole.
乘以1。,最终得到。
So this is not going to be a favorable process, we're going to find that the electron affinity is actually a negative 7 kilojoules per mole for nitrogen.
因此这并不是一个容易发生的过程,我们会发现氮的电子亲和能,应该是负的,7,千焦每摩尔。
If we want to talk about two hydrogen atoms, then we just need to double that, so that's going to be negative 2 6 2 4 kilojoules per mole that we're talking about in terms of a single hydrogen atom.
而要讨论两个氢原子,我们只需要把它乘以二,因此应该是负的,2624,千焦每摩尔,这就是单个的氢原子的情况。
And if you do so, you will end up with 1.312 mega joules per mole for this quantity K.
这样做之后,对于K常量你就能得到2,1。312百万焦耳每摩尔。
If I have one that's 400 kilojoules per mole and another that's 200 kilojoules per mole and I blend them, how do I get 500 kilojoules per mole?
如果你有一个每摩尔400千焦的分子,和一个没摩尔200千焦的分子,我把它们并子一起,我怎么得到每摩尔500千焦的键?
60 If we look at 435 times 160, take the square root of that, we will end up with 264 kilojoules per mole, which sensibly lies between these two values.
35乘以,取平方根,我们会得到264千焦每摩,很合理地落在两数值之间。
So, if we took the case of nitrogen, if we add an electron to nitrogen and go to n minus, we find that the change in energy is 7 kilojoules per mole.
如果我们以氮为例,如果我们给氮增加个电子令它变成-1价的氮,我们会发现能量的变化是,7,千焦每摩尔。
I'm averaging it over the entire set of valence electrons which gives me 1.91 MJ per mole.
我是在整个价电子的集合上作平均,最后得到1。91兆焦每摩尔。
If you flip the Periodic Table over you will have the ionization energy of sodium, first ionization energy, 5eV and it is about 5 eV which, when you convert, 496kJ/mol is a whopping 496 kilojoules per mole.
如果浏览周期表,你可以得到钠的离子化能,第一电离能,大约,当你转换的时候,是巨大的。
This means in order to do that we actually have to put 7 kilojoules per mole of energy into the reaction to make it happen.
这意味为了完成上面的反应,我们不得不往里面注入,7,千焦每摩尔的能量。
That gives us 1 mole of calcium oxide and 1 mole of carbon dioxide.
摩尔的氧化钙,和1摩尔的二氧化碳。
What is the mole? Mole is a more practical value, something that we can handle tangibly.
什么是摩尔,它有实际值,我们可以很明白的掌握的。
This is 12.011 grams per mole or 12.011 atomic mass units,AMU.
这是12。011克每摩尔,或者12。011原子质量单位。
But when the concentration in the alloy is 50/50 by mole, something magical happens.
但是当合金中的浓度,是1比1的时候,有些神奇的事发生了。
So I can make a quantity that I'll call V bar, which is the molar volume, the volume of one mole of a component in my system, and that becomes an intensive quantity.
所以我可以定义,一个叫做一横的量,这是摩尔体积系统中,一摩尔某种组分的体积,它就变成了。
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