You might have thought before we started talking about molecular orbital theory that non-bonding was the opposite of bonding, it's not, anti-bonding is the opposite of bonding, and anti-bonding is not non-bonding.

你也许在我们讨论分子轨道之前,就想过非成键时成键的反面，它不是，反键才是成键的反面，反键不是非成键。

麻省理工公开课 - 化学原理课程节选

Whereas in molecular orbital theory, what I'm telling you is instead we understand that the electrons are spread all over the molecule, they're not just associated with a single atom or a single bond.

而在分子轨道理论里，我要告诉你们的时,我们任为电子分布在整个分子中,它们不仅仅是和,一个原子或者一个键有关。

麻省理工公开课 - 化学原理课程节选

All right, so we can now see a little bit of what the power of molecular orbital theory is in predicting what kind of bonds we're going to see in molecules, or whether or not we'll see this bonding occur at all.

好了，我们已经可以看到一点,分子轨道理论在预测分子中,所成的键或者分子，能不能成键方面的能力了。

麻省理工公开课 - 化学原理课程节选

Molecular orbital theory, even at this very basic level, allowed us to predict that no, we're not going to see a true bond here, a strong bond.

即使在最基础的层次，分子轨道理论预计，我们不会看到一个键，一个强的键，。

麻省理工公开课 - 化学原理课程节选

So we're going to limit in our discussion in 511-1 for molecular orbital theory to diatomic molecules.

我们在这个课堂上对分子轨道1,理论的讨论仅限于双原子分子。

麻省理工公开课 - 化学原理课程节选

All right. So, today we're going to be talking about molecular orbital theory, but first I wanted to just mention, in case some of you didn't hear what the Nobel Prize was this morning, and this was in chemistry, it went to three different chemists.

好的，今天我们要讲的是,分子轨道理论，但首先我要说，以免有些同学没有听到,今天早上的诺贝尔奖，这是化学奖，它颁给了3个不同的化学家。

麻省理工公开课 - 化学原理课程节选

So in molecular orbital theory, what we did was we named orbitals based on their symmetry.

在分子轨道理论中，我们基于轨道的对称性给它们命名。

麻省理工公开课 - 化学原理课程节选

But let's go ahead and start our discussion in terms of molecular orbital theory.

让我们从,分子轨道理论开始讲起。

麻省理工公开课 - 化学原理课程节选

So, molecular orbital theory, on the other hand, is based on quantum mechanics.

另一方面分子轨道理论，是基于量子力学的。

麻省理工公开课 - 化学原理课程节选

So we're going to finish talking about molecular orbital theory, we'll switch over to discussing bonding in larger molecules, even larger than diatomic, so we'll move on to talking about valence bond theory and hybridization.

我们要结束关于分子轨道理论的讨论，转向讨论大分子的成键，比二原子分子更大的分子，我们会继续讨论价电子成键理论,和杂化。

麻省理工公开课 - 化学原理课程节选

But first, I just want to remind you when we're talking about molecular orbital theory, this is treating electrons as waves, so what we're actually able to do is either constructively or destructively combine atomic orbitals to form molecular orbitals.

但首先，我要提醒你们,当我们讨论，分子轨道理论的时候，我们把电子看作是一种波,所以我们可以相长叠加,或者相消叠加这些原子轨道来组成分子轨道。

麻省理工公开课 - 化学原理课程节选

Today we're talking about molecular orbital theory.

今天我们要讲的是分子轨道理论。

麻省理工公开课 - 化学原理课程节选

And what I want to point out that we just figured out for molecular orbital theory, is that o 2 is a biradical, because remember, the definition of a radical is when we have an unpaired electron.

我要指出的是,我们刚利用分子轨道理论，指导了O2是二价自由基，因为记住，自由基的定义是,有个未配对的电子。

麻省理工公开课 - 化学原理课程节选

And there's actually a way that we can make predictions here, and what I'll tell you is molecular orbital theory predicts that h e 2 does not exist because it's not stabilized in terms of forming the molecule.

其实我们有一种办法可以做出预测，我要告诉你们的是分子轨道,理论预测He2不存在,因为它形成分子不稳定。

麻省理工公开课 - 化学原理课程节选