And Pauli says no two electrons in a given system can have the entire set of quantum numbers identical.
而泡利认为在一个给定的系统内,没有两个电子有完全相同的量子数。
The first one is the Pauli Exclusion Principle which was enunciated by Wolfgang Pauli.
第一部分是泡利不相容原则,由沃尔夫冈,泡利做了详尽阐释。
Pauli So let's try a clicker question and thinking about the Pauli exclusion principle.
让我们看一个关于,不相容原理的习题。
The idea could be summed up by a quotation from the physicist Wolfgang Pauli.
这种批评可以用物理学家,沃尔夫冈·泡利的一句话来进行概括。
And we are going to use the Pauli Exclusion Principle and we are going to use the fact that we fill from lower energy to higher energy.
我们将会用到泡利不相容定律,而且我们准备利用这个事实,那就是我们从低能级到高能级填充。
That includes Pauli Exclusion Principle and includes Hund's Rule and so on.
包括保利不相容原理,和洪特原理等等。
And once they start to become part of one system, Pauli Exclusion Principle kicks in.
一旦他们开始成为体系的一部分,泡利不相容原理起作用了。
One is the Pauli exclusion principal, we discussed this on Wednesday.
一个是泡利不相容原理,我们在周三讨论过它。
What did he do? Well, he studied with Pauli.
他做过些什么,他曾和泡利一起学习过。
Hmm, OK. So, Pauli seems to be getting a little bit of fame that you'll see in a second here.
嗯,ok,看来Pauli的名气,更大一些。
He and Pauli were buddies in graduate school.
在读研究生的时候他们是好伙伴。
And Pauli said this: "That guy's work is crap.
泡利说,“那家伙的研究烂透了。
Pauli was an Austrian who did his PhD under Sommerfeld in Munich and then post-doced with Max Born in Gottingen and also with Niels Bohr in Copenhagen.
泡利是个奥地利人,他在慕尼黑读博的时候导师是索末菲,他后来从医的时候,在哥廷根和曼克斯·波恩共事,在哥本哈根的时候和尼根斯·波尔共事。
And you are saying wait a minute, he has violated the Pauli Exclusion Principle.
你们有人在喊我停一下,说我违反了保利不相容原理。
That would violate Pauli.
那违背了洪特定律。
Pauli So, here, Pauli came out on top, we say, and he's known for the Pauli exclusion principle, which tells us that no two electrons in the same atom can have the same four quantum numbers.
在这里是,他因为Pauli不相容原理而出名,这个原理是说同一个原子中的两个电子,不能有相同的第四量子数。
So the person they chose to talk to, Wolfgang Pauli and I think it was just Goudsmit that went to him and discussed it is Wolfgang Pauli, Pauli which is shown here.
所以他们选择,讨论的人是,我觉得仅仅是Goudsmit去和他讨论了,这就是。
And Pauli was asked his opinion about another physicist.
有人问泡利对另一个物理学家的看法。
Pauli How about Pauli, like the Pauli exclusion principle?
有多少人听说过,就是Pauli不相容原理的Pauli?
So we have two electrons in our bonding orbital, but because we use the same rules to fill up molecular orbitals as we do atomic orbitals, so the Pauli exclusion principle tells us we can't have more than two electrons per orbital, so we have to go up to our anti-bonding orbital here.
所以在成键轨道上有两个电子,但因为我们用了和原子轨道时,用的相同的规则,所以Pauli不相容原理告诉我们,一个轨道上不能有两个以上的电子,所以我们需要填充到反键轨道上去。
And in chemistry, just like in any discipline, you have all types of scientists, but also all types of personalities, and unfortunately Pauli had a personality that was known for, first of all, being very arrogant, but also the very unfortunate trait of taking other people's scientific ideas as his own.
在化学里,就像在任何学科中一样,有各种各样的科学家,也就有各种各样的性格,不幸的是,Pauli的性格,是以傲慢闻名,另外一个特点就是喜欢,把别人的观点占为己有。
应用推荐