So for example I defined p, remember back over here, as a Cartesian point, but I can actually ask for its polar form.
我可以要求返回它的极坐标形式,这里对我是可访问的,好,这很棒,请再记另外一个为什么。
So it's kind of the polar opposites,
虽然这两种是截然相反的衣服,
So, we know from our calculation that we can do over here, that this bond is polar.
我们通过计算都知道,这个键是非极性的。
Another reason I wanted to point this out in terms of the polar coordinates that we're using, is I think they're actually flipped from what you're used to seeing in physics.
另一个我想指出,我们采用极坐标的原因是,我认为它们实际上是,从你们习惯于看到的物理学中出来的。
the same as polar point 2, polar point 1 And then I could say well, gee, are they the same point?
和另外一个极坐标点,我如果来试试,和polar,point,2是不是相同的话?
In terms of the Schrodinger equation, we now can write it in terms of our polar coordinates here.
在薛定谔方程中,我们现在可以用,极坐标的方式来表示了。
The second way to have something that is net nonpolar is to have spatially symmetric disposition of polar bonds.
第二种构成,需要空间非极性,就是需要极性键的空间对称分布。
This is pure covalency. This is polar covalency.
这是平均共价,它是极性共价。
A good example of that is CH4, because the CH bond is polar but symmetrically disposed in space.
甲烷就是一个很好的例子,因为极性键是,空间对称的。
I could imagine writing another function for same point, and I have to give it a name like same point polar, and same point Cartesian.
程序不知道怎么来做了,它没有对应的处理方法,所以它要抱怨了,那么我这里的问题就是,这也是我一直想要说的。
If it's in polar form I passed in a radius and angle and I'll compute what the x- and y- value is.
以及半径和角度,但是现在是这样的,不管我是以哪种形式。
Because this is a dipole, he chose the pole part of dipole to give us polar covalency.
这就是偶极,鲍林选择了偶极中“极“这一部分来,组成极性共价这个词向我们诠释。
Here is the question. Is methane a polar molecule or a nonpolar molecule? Let's look carefully.
问题是,甲烷是一个极性分子还是非极性分子,我们仔细看看。
And then I could do things like again, say, okay having done, that let me just run it here, run that, so I've now got polar point 1, and polar point 2.
然后给它们赋值半径和角度,然后我可以进行刚才的操作,也就是说,对刚才的笛卡尔坐标进行的操作,让我们来运行下它吧,运行下,现在我有一个极坐标点。
I've got a definition of Cartesian point, I've got a definition of polar point.
让我们运行这个程序,来把应用这些定义。
We only have the one bond so the actual HF molecule is polar, it has a net dipole.
但HF中只有一根键,所以分子也是极性的而甲烷中有一个网状偶极。
So you can see that polar covalency is a tendency towards ionic bonding.
所以你看得出极性共价就是,趋向离子键的。
We know that it's non-polar.
我们都知道他是非极性分子。
How do you know whether it's in Cartesian form or in polar form?
这没什么了不起的,但是现在出现问题了?
If I now say, I'm going to go ahead and change the radius of this, something, my polar form did it right, but what happened to the Cartesian form?
如果我现在说,我要去改变这里的半径,一些这样的操作,我的极坐标形式,进行了正确的改动?
Other polar solids, we will have to come back to that later.
其它的极性固体,我们在后面会讲到这一点。
I could do the same thing, I could build polar point.
很多笛卡尔点,我可以做一些同样的操作。
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