So what they do is, they're describing how these thermodynamic properties change, in terms of only state functions and state variables.
他们的作用是描述,随着状态函数和状态变量的变化,系统的热力性质如何变化。
All right, so this is the heat flowing in or out of the system, and these are all functions of state.
好的,这就是系统的热量变化,这些都是态函数。
are all functions of state and parameters that we can control like temperature and pressure.
公式里面的全部都是态函数,我们控制态函数的参数比如温度或者压强。
Delta u, delta H, familiar state functions, q w changes in their values, q, w, heat and work.
U,△H,很熟悉的态函数,它们的值在变化;
But since these are all simply state functions and quantities, this is generally true.
但是因为这些量都是态函数或者量,所以这个结果是普遍成立的。
This is very different from the functions of state like pressure and temperature.
联系初末两态的整个过程,这与压强。
There's no change in them, and then we also looked at some at non-state functions, work and heat, and saw that those aren't zero going around a cycle. Of course you can do work in a cyclic process, and heat can be exchanged with the environment at the same time.
它们不会有变化,然后我们研究了,一些非态函数,功和热量,并看到,沿着循环行进一周的话,它们并不是零,当然你可以在,一个循环过程中做功,而同时热量可以在系统,与外界环境之间进行交换。
So now, this equation here relates three state functions together: the pressure the volume, and the temperature. Now, if you remember, we said that if you had a substance, if you knew the number of moles and two properties, you knew everything about the gas.
压强,体积和温度,大家应该还记得,我们提过,只要知道气体的摩尔数,和任意两个状态函数,就可以推导出其他的状态函数,这样,我们可以把它改写成。
G Here, A and G, we've already got as functions of these easily controlled, conveniently controlled state variables.
这里,A和,我们已经把它们写成了,容易控制的状态变量的函数。
And it's more dramatic if the system is a gas p T2 V2 p, T2, V2, And let's look at what happens to U these functions of state, to H to u under this transformation.
如果是气体这个系统,就更具有趣了,让我们看看H和,在这个变化中态函数会发生什么变化。
Cv The only difference is it'll be Cp instead of Cv, B but there it is for pathway B. There it is for C a pathway C. So the state functions that we're familiar with are doing what we expect they ought to be doing, right? If you go around in a cycle, starting and ending at the same place the state functions have to stay the same.
是Cp而不是,这是路径,这是路径,所以我们熟悉的态函数的行为,正与我们预期的相同,对吧?,如果你沿着循环走一圈,开始和结束于同一个位置。
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