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OK, so now we've got, taken an electron from that sulfur, put it here, an electron from that sulfur, put it here.
现在我们得到的是，从硫那儿得到一个电子，放在这儿，一来自于硫的电子，放在这儿。
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times 7, plus we have 6 in the sulfur, and oxygen is right above sulfur, so that also has 6.
二乘上七，加上硫的六个，而氧在硫的正上方，因此也有六个。
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2 3 Well, son of a gun, one, two, three, four, five, six, sulfur, We've got six. We've used all the electrons.
真见鬼，4，5，6，硫，共六个，我们已经用掉了所有的电子。
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So why don't you tell me what the formal charge should be on the sulfur atom of thionyl chloride?
那么请大家来告诉我亚硫酰氯中,的硫原子应该有多少形式电荷？
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So, if we compare the sulfur to the oxygen, the oxygen it turns out is more electronegative and that is what holds the negative charge in this molecule.
因此，如果我们来比一下硫和氧，氧应该有更高的电负性,而在这个分子中它确实有负的电荷。
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It could be aluminum, silicone, phosphorous, sulfur, c hlorine or argon.
答案可能是铝，硅，磷，硫,氯或者氩。
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So between b e, and b, between n and o, magnesium and aluminum, and then phosphorous and sulfur, what we see here is that we're kind of going down, or quite specifically, we are going down.
比如从铍到硼，从氮到氧，从镁到铝，从磷到硫，我们在这些地方看到有点下降，或者可以明确地说，我们确实在下降。
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090 We have 1,090 for carbon, 1000 1,000 for sulfur, 1400 and 1,400 for nitrogen.
碳的是，硫的是，而氮的是。
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And then we end up having 6 shared electrons, 2 from each of the bonds, so we end up with a formal charge on sulfur of plus 1.
然后我们有六个共用电子，每个键两个，因此最终硫的形式电荷量为正一。
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All right. So, let's go ahead and draw our Lewis structure here with sulfur in the middle.
好，那么，让我们来把我们的,路易斯结构画在这，硫在中间。
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For the sulfur, we start off with 6 valence electrons, minus 4 lone pair electrons, minus 2, taking in account our bonding electrons, so we end up with a formal charge of 0.
对于硫，我们从六个价电子开始，减去四个孤对电子，再减去二，算上我们的成键电子，因此最终我们有零个形式电荷。
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We would expect the ionization energy to decrease, that means that sulfur has our lowest ionization energy.
我们预期电离能会降低，这就意味着硫的电离能最低。
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He said look at sodium, magnesium, aluminum, silicon, phosphorus, sulfur, chlorine, potassium.
他说，看，钠，镁，铝，硅，磷，硫磺，氯，钾。
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So, we can put our sulfur in the middle, and then it doesn't really matter how we draw the rest of it, where we put our c l's versus where we put our oxygen.
那么，我们可以把硫放在中间，然后把其它的原子画在哪里就不重要了，把两个氯原子与一个氧原子放在哪里都行。
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So if we look at sulfur, what we need to do is take the valence electrons in sulfur, and there are 6.
因此如果我们来看硫原子的话，我们需要做的是,将硫的价电子，有六个。
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And what we have left here is the sulfur, which will also get a pair.
剩下的是硫，它也应该得到一对。
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So in one case, we could actually put carbon in the middle, in one place, we could put sulfur in the middle, and in one case we could put nitrogen.
那么有一种情况是，我们把碳放在中间，还有一种情况是，把硫放在中间，另外一种情况是把氮放在中间。
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But, the oxygen has taken two electrons from the sulfur.
但是，氧从硫那里得到了2个电子。
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And, this is all that was known at that time, seven metals, carbon, and sulfur.
这是当时所知道的了，7种金属，碳，和硫磺。
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So, in terms of ionization energy, we would expect to see sulfur in the middle.
因此，按照电离能，我们应该把硫放在中间。
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We started with just the seven metals and carbon plus sulfur, it was the point of departure for Democritus.
我们开始讲了7种金属,还有碳和硫磺，那就是Democritus的起点。
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So, a lot of people I hear are saying sulfur, and that's right.
我听到很多人说的是硫，这是正确的。
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Well, this chlorine has taken one electron from the sulfur.
对了，这个氯从硫那里得到了一个电子。
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And what you find out if you do these calculations, is that you have a negative 1 for your formal charge on nitrogen, you have a negative 2 for your formal charge on carbon, and you have a positive 2 for your formal charge on sulfur.
而如果你做了这些计算会发现，氮的形式电荷量为负一，碳的形式电荷量为负二，而硫的形式电荷量为正二。
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We'll just put them in some way around our sulfur atom.
我们只要随便把它们放在硫原子周围就行了。
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