• So, now with this framework, I said that talking about these valence electrons might give us some insight into chemical reactivity.

    所以,现在对于这个结构,我认为讨论价电子能,会让我们对化学反应有更深的领悟。

    麻省理工公开课 - 固态化学导论课程节选

  • So, what we do as our seventh step is then figure out if we have any extra valence electrons left at all.

    那么,第七步要做的是看看,我们还有没有剩下的价电子。

    麻省理工公开课 - 化学原理课程节选

  • And, at the other extreme, we have elements with very high value, elements with high average valence electron energy.

    另外,在另一端,我们有原子序数较大的元素,这些元素有着较高的平均化合价和电子能。

    麻省理工公开课 - 固态化学导论课程节选

  • So we started with 10 valence electrons, we used up 8 of those electrons in terms of making bonds.

    我们一开始有十个价电子,然后用掉了八个电子来成键。

    麻省理工公开课 - 化学原理课程节选

  • CO Right, so you take the co here, and we take the valence here, and out of that comes covalent.

    好了,然后我们看到,我们可以看到他的化合价,他们成共价键。

    麻省理工公开课 - 固态化学导论课程节选

  • OK, then it says draw a single bond from each surrounding atom to the central atom, and subtract two valence electrons.

    后将中心原子与其相邻原子之间,连上单键,然后减掉2个价电子。

    麻省理工公开课 - 固态化学导论课程节选

  • if we're actually thinking about electron configuration and we look at lithium, sodium and potassium, these all have one valence electron.

    让我们来想一想,锂,钠,钾的电子排布,它们都只有一个价电子。

    麻省理工公开课 - 化学原理课程节选

  • OK, elements with low average valence electron energy, and here I'm saying below 11 electron volts, these are good electron donors.

    平均价电子能都较低的元素,我是指那些低于11电子伏的,这些是很好的电子给体。

    麻省理工公开课 - 固态化学导论课程节选

  • Its average valence electron energy is 5.2 electron volts, which is a heck of a lot less than 11.

    它的平均价电子能是,5。2电子伏,那比11电子伏要少得多。

    麻省理工公开课 - 固态化学导论课程节选

  • Over here in the lower left corner, we have elements that as a group have very low values of average valence electron energy.

    在底层的左侧角落,我们看到以组为单位的,价电子能较低的元素。

    麻省理工公开课 - 固态化学导论课程节选

  • So, seven asks us if we have any valence electrons left, and how many valence electrons do we have left?

    那么,第七步问我们是否还有价电子剩下,我们剩下了几个价电子?

    麻省理工公开课 - 化学原理课程节选

  • So in terms of total numbers that we would need to complete our octets and fill our valence shells, we would need 18 electrons.

    因此要填满我们的“八隅体“,排满所有的价壳层,我们总共需要十八个电子。

    麻省理工公开课 - 化学原理课程节选

  • In this case, 6 valence electrons for each oxygen, so we have 18 total valence electrons.

    在这种情况下,每个氧原子都有六个价电子,因此我们总共有十八个价电子。

    麻省理工公开课 - 化学原理课程节选

  • So, in this case, we're just drawing the molecular orbital diagram for the valence electrons, so we have three for each.

    所以在这个例子里面,我们只需要画出,价电子的分子轨道图,所以每个有3个电子。

    麻省理工公开课 - 化学原理课程节选

  • The reason is because we already have a full valence shell for our hydrogen, it doesn't want any more electrons.

    原因是因为我们的氢,已经有一个排满的价壳层了,它不再需要多余的电子了。

    麻省理工公开课 - 化学原理课程节选

  • And we do so by a quantity called the average valence electron energy.

    我们可以通过,一个叫做平均价电子能的量来解决这一问题。

    麻省理工公开课 - 固态化学导论课程节选

  • For the carbon, we start with 4 valence electrons, we have 0 lone pair electrons minus 4, and we end up with a formal charge of 0.

    对于碳,我们从四个价电子开始,我们有零个孤对电子,再减去四,最终我们有零个形式电荷。

    麻省理工公开课 - 化学原理课程节选

  • We have to account for that in some way because we know that they don't have identical average valence electron energies.

    我们需要从一些方面来解释一下,因为我们都知道,他们没有相同的,平均价电子能。

    麻省理工公开课 - 固态化学导论课程节选

  • So we have a total of 2, 4, 6, 8, 10 valence electrons, so I'll make sure I count to 10 as we fill up our molecular orbitals here.

    我们一共有2,4,6,8,10个价电子,所以我一边填一边要确认,我数到10。

    麻省理工公开课 - 化学原理课程节选

  • Yeah, so also 4. We started with 10 valence electrons, we used up 6 of those as bonding electrons, so we have 4 left, which will be lone pair electrons.

    对,也是四个,我们从十个价电子开始,只用了六个来成键,因此我们还剩下四个,它们将成为孤对电子。

    麻省理工公开课 - 化学原理课程节选

  • So in terms of remaining valence electrons we have 12, so we can finish off each of our Lewis structures, so that's our first structure there, and our second structure there.

    那么关于剩下的价电子,我们有十二个,因此我们可以完成这两个路易斯结构了,那么这是我们的第一个结构,而那是我们的第二个结构。

    麻省理工公开课 - 化学原理课程节选

  • Step three in our Lewis structure rules is to figure out how many electrons we would need in order for every single atom in our molecule to have a full valence shell.

    路易斯结构规则的第三步是,找出让分子中每个原子的价壳层,都排满应该需要多少个价电子。

    麻省理工公开课 - 化学原理课程节选

  • OK PROFESSOR: Valence electrons. OK, sometimes you're going to be asked to draw a molecular orbital diagram where you're asked to include all electrons, and sometimes it will specifically say only include valence electrons.

    教授:价电子,有时候你画一幅分子轨道图,有时候要求你画出所有的电子,有时候特别要求,只包括价电子。

    麻省理工公开课 - 化学原理课程节选

  • So the 3 s 1, or any of the other electrons that are in the outer-most shell, those are what we call our valence electrons, and those are where all the excitement happens.

    它们是经常发生激发情况的,那也是我们所看到,我们称之为价电子,它们是经常发生激发情况的。

    麻省理工公开课 - 化学原理课程节选

  • And the idea is that when you do these Lewis dot structures, we're representing electrons with dots, which we'll see in a minute, and each dot is going to represent a valence electron.

    而当你遇到这些路易斯点结构时,我们会将电子用点来表示,我们马上就会看到,每个点都代表了一个价电子。

    麻省理工公开课 - 化学原理课程节选

  • So in terms of nitrogen that starts off with a valence number of 5, again we have 2 lone pair electrons in the nitrogen, and again, we have 6 electrons that are shared.

    对于氮来说,我们应该从五个价电子开始,同样,氮也有两个孤对电子,共用电子的个数也一样,是六个。

    麻省理工公开课 - 化学原理课程节选

  • So then, I could say that the average valence electron energy for oxygen would then be, I've got two s electrons.

    所以,我可以说,氧的平均价电子能,就是,以我得到的两个s轨道的电子来算。

    麻省理工公开课 - 固态化学导论课程节选

  • It's got an average valence electron energy of about 16 eV, 16.5 eV, which is a lot greater than 11.

    它的平均价电子能,大约是16eV,16。5eV,那比11要多很多。

    麻省理工公开课 - 固态化学导论课程节选

  • All right, so that's really all there is to thinking about valence bond theory in terms of the most simple explanation here.

    好了,这就是,价电子轨道理论的,最简单的解释。

    麻省理工公开课 - 化学原理课程节选

  • So in oxygen again, this is just showing the valence electrons, so we end up having six valence electrons from each oxygen atom.

    所以在氧里面,这里只展示价电子,我们最后每个氧得到6个价电子。

    麻省理工公开课 - 化学原理课程节选

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