So, now with this framework, I said that talking about these valence electrons might give us some insight into chemical reactivity.
所以,现在对于这个结构,我认为讨论价电子能,会让我们对化学反应有更深的领悟。
So, what we do as our seventh step is then figure out if we have any extra valence electrons left at all.
那么,第七步要做的是看看,我们还有没有剩下的价电子。
And, at the other extreme, we have elements with very high value, elements with high average valence electron energy.
另外,在另一端,我们有原子序数较大的元素,这些元素有着较高的平均化合价和电子能。
So we started with 10 valence electrons, we used up 8 of those electrons in terms of making bonds.
我们一开始有十个价电子,然后用掉了八个电子来成键。
CO Right, so you take the co here, and we take the valence here, and out of that comes covalent.
好了,然后我们看到,我们可以看到他的化合价,他们成共价键。
OK, then it says draw a single bond from each surrounding atom to the central atom, and subtract two valence electrons.
后将中心原子与其相邻原子之间,连上单键,然后减掉2个价电子。
if we're actually thinking about electron configuration and we look at lithium, sodium and potassium, these all have one valence electron.
让我们来想一想,锂,钠,钾的电子排布,它们都只有一个价电子。
OK, elements with low average valence electron energy, and here I'm saying below 11 electron volts, these are good electron donors.
平均价电子能都较低的元素,我是指那些低于11电子伏的,这些是很好的电子给体。
Its average valence electron energy is 5.2 electron volts, which is a heck of a lot less than 11.
它的平均价电子能是,5。2电子伏,那比11电子伏要少得多。
Over here in the lower left corner, we have elements that as a group have very low values of average valence electron energy.
在底层的左侧角落,我们看到以组为单位的,价电子能较低的元素。
So, seven asks us if we have any valence electrons left, and how many valence electrons do we have left?
那么,第七步问我们是否还有价电子剩下,我们剩下了几个价电子?
So in terms of total numbers that we would need to complete our octets and fill our valence shells, we would need 18 electrons.
因此要填满我们的“八隅体“,排满所有的价壳层,我们总共需要十八个电子。
In this case, 6 valence electrons for each oxygen, so we have 18 total valence electrons.
在这种情况下,每个氧原子都有六个价电子,因此我们总共有十八个价电子。
So, in this case, we're just drawing the molecular orbital diagram for the valence electrons, so we have three for each.
所以在这个例子里面,我们只需要画出,价电子的分子轨道图,所以每个有3个电子。
The reason is because we already have a full valence shell for our hydrogen, it doesn't want any more electrons.
原因是因为我们的氢,已经有一个排满的价壳层了,它不再需要多余的电子了。
And we do so by a quantity called the average valence electron energy.
我们可以通过,一个叫做平均价电子能的量来解决这一问题。
For the carbon, we start with 4 valence electrons, we have 0 lone pair electrons minus 4, and we end up with a formal charge of 0.
对于碳,我们从四个价电子开始,我们有零个孤对电子,再减去四,最终我们有零个形式电荷。
We have to account for that in some way because we know that they don't have identical average valence electron energies.
我们需要从一些方面来解释一下,因为我们都知道,他们没有相同的,平均价电子能。
So we have a total of 2, 4, 6, 8, 10 valence electrons, so I'll make sure I count to 10 as we fill up our molecular orbitals here.
我们一共有2,4,6,8,10个价电子,所以我一边填一边要确认,我数到10。
Yeah, so also 4. We started with 10 valence electrons, we used up 6 of those as bonding electrons, so we have 4 left, which will be lone pair electrons.
对,也是四个,我们从十个价电子开始,只用了六个来成键,因此我们还剩下四个,它们将成为孤对电子。
So in terms of remaining valence electrons we have 12, so we can finish off each of our Lewis structures, so that's our first structure there, and our second structure there.
那么关于剩下的价电子,我们有十二个,因此我们可以完成这两个路易斯结构了,那么这是我们的第一个结构,而那是我们的第二个结构。
Step three in our Lewis structure rules is to figure out how many electrons we would need in order for every single atom in our molecule to have a full valence shell.
路易斯结构规则的第三步是,找出让分子中每个原子的价壳层,都排满应该需要多少个价电子。
OK PROFESSOR: Valence electrons. OK, sometimes you're going to be asked to draw a molecular orbital diagram where you're asked to include all electrons, and sometimes it will specifically say only include valence electrons.
教授:价电子,有时候你画一幅分子轨道图,有时候要求你画出所有的电子,有时候特别要求,只包括价电子。
So the 3 s 1, or any of the other electrons that are in the outer-most shell, those are what we call our valence electrons, and those are where all the excitement happens.
它们是经常发生激发情况的,那也是我们所看到,我们称之为价电子,它们是经常发生激发情况的。
And the idea is that when you do these Lewis dot structures, we're representing electrons with dots, which we'll see in a minute, and each dot is going to represent a valence electron.
而当你遇到这些路易斯点结构时,我们会将电子用点来表示,我们马上就会看到,每个点都代表了一个价电子。
So in terms of nitrogen that starts off with a valence number of 5, again we have 2 lone pair electrons in the nitrogen, and again, we have 6 electrons that are shared.
对于氮来说,我们应该从五个价电子开始,同样,氮也有两个孤对电子,共用电子的个数也一样,是六个。
So then, I could say that the average valence electron energy for oxygen would then be, I've got two s electrons.
所以,我可以说,氧的平均价电子能,就是,以我得到的两个s轨道的电子来算。
It's got an average valence electron energy of about 16 eV, 16.5 eV, which is a lot greater than 11.
它的平均价电子能,大约是16eV,16。5eV,那比11要多很多。
All right, so that's really all there is to thinking about valence bond theory in terms of the most simple explanation here.
好了,这就是,价电子轨道理论的,最简单的解释。
So in oxygen again, this is just showing the valence electrons, so we end up having six valence electrons from each oxygen atom.
所以在氧里面,这里只展示价电子,我们最后每个氧得到6个价电子。
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