The inner electrons are so tightly bound that they are for all intents and purposes, immobilized when it comes to reactivity.
内部电子被紧紧地束缚着,因此无论怎样,当进行反应时,它都是固定的。
And, in fact, if any electron comes in their midst, they'll capture it because the binding energy is so high.
事实上,如果电子从中间进来,它们会捕获它,因为束缚能是如此之大。
So I said that this technique was used to experimentally determine what the different binding energies or the different ionization energies are for the different states in a multielectron atom.
我说过,这项技术被用来,在实验上确定多电子原子的,各个不同态相应的束缚能,或者电离能。
So, remember when we talk about Coulomb force, what's holding the nucleus and the electron together, there's 2 things we need to think about.
还记得我们在讨论库仑力的时候,提到是什么将原子核与电子束缚在一起时,有两点需要考虑。
And, as I mentioned, we left off and as we started back here to describe the atom and how the atom holds together the nucleus and the electron using classical mechanics.
我之前提及过,我们上次,讲到应用经典力学如何描述,一个原子以及原子如何把质子,和电子束缚在一起,今天我们要。
And so the energy is zero because the electron is no longer bound. It is free.
所以这个系统能量为0,因为,电子不再受束缚了,它自由了。
So, if we want to go from that stable state to that less stable state, we need to put in a certain amount of energy to our system, that difference between the free electron and the electron bound to the metal.
所以,如果我们想使电子,从稳态到达不够稳定的状态,我们需要引入一定数量的,能量到系统中,即自由电子和束缚于金属的,电子的能量差。
They are good electron donors because the electrons aren't tightly bound.
它们是很好的电子给体,因为电子没有被牢固地束缚。
And that's going to be equal to the negative the binding energy of 2 s in b, in neutral boron.
它应该等于中性硼原子中,2,s,电子的束缚能的负值。
That is to say it is confined to the atom.
也就是说电子会被束缚在原子内。
So, that means the electrons are tightly bound.
所以那意味着这些电子是被紧紧地束缚着的。
So we can think about what is our most loosely-bound electron, what's that highest energy orbital, and it's going to be the 2 p orbital, that's going to be what's highest in energy.
我们来想一想,它“束缚得最松“的电子是哪一个,能量最高的轨道是哪一个?,它就是,2,p,轨道,是能量最高的轨道。
It makes a lot of sense when we look at it energetically, because if we think about a 1 s core electron, that's going to be held really, really tightly to the nucleus.
从能量的观点来看这是非常合理的,因为如果我们考虑一下,1,s,芯电子,它会被原子核束缚得非常非常紧。
So here we have energy increasing on the y-axis, and you see this straight line at the bottom here is lower down on the graph, and that's the energy of a bound electron, so that's going to be a low stable energy.
这里我们看到能量沿着y轴增加,而且在这张图片上,这条直线在底部是降低的,那是一个束缚电子的能量,所以那是一个低稳态能量。
Core electrons are all those electrons held in really tight with the nucleus in the inner shells, whereas the valence electrons are only those electrons that are in the outer-most shell, or at your highest value of n of the principal quantum number.
芯电子是那些,在内壳层被原子核束缚得非常紧的电子,而价电子只包括,最外层的电子,或者说主量子数,n,的值最大的那些电子。
And what we say when we talk about the delta energy is I E 2 that this is going to be equal to i e 2, or the second ionization energy, or we could say the negative of the binding energy of a 2 s electron in b plus.
那么我们说,Δ,E,应该等于,或者说第二电离能,也就是正一价硼中,2,s,电子的,束缚能的负值。
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