This is the electronic partition function.
这是电子的配分函数。
OK. So this is your molecular partition function.
好,这就是分子配分函数。
And the system partition function is labeled big Q.
系统的配分函数用Q标记。
Now, qi is just the total molecular partition function.
现在qi是分子总配分函数。
We also know what the vibrational partition function is.
我们也知道振动能的配分函数。
So now let's figure out our molecular partition function.
现在我们来计算分子的配分函数。
You can also look at the molecular partition function itself.
对单个分子的配分函数本身也适用。
We can write the partition function as a sum over energy level.
我们可以把配分函数写成,对能级的求和。
You also have the system partition function for the configurations.
同样的,对构型部分,也是分子构型配分函数的N次方。
Then you can have a partition function for each of these degrees of freedom.
都有对应的配分函数,每个自由度。
Q And now the total system partition function is the multiplication of these two.
总配分函数,是这两者之积。
Q And now the total system partition function is the multiplication of these two.
总配分函数,是这两者之积。
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