同时它也可以作为手性配体应用于不对称合成。
It is also widely used in asymmetric synthesis as chiral auxiliaries.
综述了这类手性配体在不对称催化反应中的应用。
Applications of these planar chiral ligands in asymmetric catalysis are reviewed.
因此，手性催化反应的关键是手性配体的设计与合成。
So the key of asymmetric reaction is design and synthesis of the chiral ligands.
一种化工技术领域的1，2-取代二茂钌面手性配体及其合成方法。
The present invention relates to 1, 2- substitute cyclopentadienyl ruthenium surface chiral ligand in the chemical field and the correspondence synthetic method.
不对称催化研究中，手性配体(催化剂)的合成是非常重要的部分。
The synthesis of chiral ligands (or catalysts) is a very important part in the research of asymmetric catalysis.
综述了近几年来手性配体与铑的配合物在不对称催化氢化研究的新进展。
The recent progress of the chiral ligands-Rhodium complexes in asymmetric catalytic hydrogenation were reviewed in this paper.
共包括四个子课题：1。手性配体高聚物的合成及D、L-氨基酸的光学拆分；
The item consisting of four parts: 1. syntheses of chiral ligand polymer of optical resolution of D, L-amino acids;
综述了手性配体金属络合物催化剂催化1,3 -偶极环加成反应的研究进展。
The research advances of the chiral ligands metal complexes catalysts used in asymmetric 1, 3-dipolar cycloaddition reactions were reviewed in this paper.
手性亚砜及其衍生物广泛作为重要手性辅剂、手性配体、手性催化剂、手性药物。
Chiral sulfoxides and their derivatives are extensively used as important chiral intermediates, auxiliaries, chiral ligands, catalysts, and chiral drugs.
在手性催化反应中，手性配体是不对称诱导的手性源，控制着反应的立体化学过程。
As the chiral source of asymmetric induction, the chiral ligands control the procedure of stereochemistry in reaction.
手性亚砜及其衍生物广泛作为重要手性中间体和辅剂、手性配体和催化剂、手性药物。
Chiral sulfoxides and their derivatives are extensively used as important chiral intermediates and auxiliaries, chiral ligands and catalysts, and chiral drugs.
手性催化剂的制备是不对称催化合成的关键，其中手性配体的研究是一个重要的研究方向。
The chiral catalysts play the key role in the asymmetric catalytic synthesis, in which the chiral ligands are essential.
综述了近年来联萘衍生物作为手性配体构成的金属络合物在前手性烯、酮及亚胺的不对称氢化反应中的应用。
In this article, the recent application in recent years of metal complexes composed of binaphthyl derivatives in asymmetric hydrogenation of prochiral alkenes, ketones and imines are reviewed.
本发明的合成方法简便直接，从外消旋的螺环二酮出发得到螺环骨架具有不同绝对构型的光 学纯的手性配体。
The synthetic method is simple and convenient and direct; and the spiral ring skeleton obtained from spiro-diketone has optical pure chiral ligand with different absolute configurations.
报道了一系列衍生自9，10-二氢菲-9，10-二醇的新型手性配体设计、合成及在不对称催化反应中的应用。
A series of novel chiral ligands derived from (9,10)-dihydrophenanthrene-9,10-diol were designed , synthesized and applied in some asymmetric catalysis.
综述了手性1，2二苯基1，2 乙二胺及其衍生物的合成，以及作为手性辅助基和手性配体在不对称合成中的应用。
This review summarizes the synthesis and the application of 1,2-diphenyl- 1,2-diaminoethane and its derivatives as chiral auxiliaries, chiral ligands and chiral reagents in asymmetric synthesis.
按配位原子的数目和种类进行分类，综述了近年来含硫的手性配体在有机锌试剂和醛等化合物的不对称加成反应中的最新研究进展。
Recent developments in organozinc reagents on asymmetric addition catalyzed by sulfur-containing chiral ligands are reviewed according to the type and number of the coordinating atoms.
关于手性配体催化二烷基锌一羰基的不对称加成生成光活性醇的反应，从催化剂、不对称催化机理与自催化过程、手性放大等方面进行了概述，参考文献50篇。
The title reaction is reviewed with 50 references, the catalysts, the mechanism of asymmetric catalysis, the self-catalyzed process and the chiral amplification phenomenon are discussed.
手性氨基醇是一类具有很大发展潜力的用于催化不对称合成反应的配体或催化剂。
Chiral amino alcohol is a kind of the ligand or catalyst with great potential for the development of catalytic asymmetric synthesis.
综述了手性氨基醇作为配体或催化剂在不对称合成中的应用及最新进展。
The applications and recent progresses of chiral amino alcohols as either ligands or catalysts in asymmetric synthesis are reviewed.
又考察一些手性二醇配体，其中，茚衍生的配体有着较好的手性诱导性能。
Some chiral diols were also investigated as the ligands, with those derived from indene exhibiting better enantioselectivity.
建立了配体交换色谱手性流动相法拆分茶氨酸对映体的方法。
Ligand exchange chromatography with chiral mobile phases was established for the separation of theanine enantiomers.
本论文的另一部分工作是合成了L -脯氨酸衍生的系列手性磺酰胺配体。
In this thesis, the synthesis of series of chiral sulfonamide ligands which were derived from L-proline is our another part of work.
以价廉的天然产物辛可宁和奎宁为原料，在温和的条件下方便地合成了两个手性膦氮配体。
Two chiral P, N-ligands were synthesized in high yields from natural quinine and cinchonine under mild conditions.
本文综述了手性膦配体及其碳碳双键的不对称催化氢化反应研究和最新进展，并对手性膦配体的设计做了分析和总结。
The paper reviewed the study on the chiral phosphines in asymmetric catalytic hydrogenation and their nearest development. Thedesign of chiral phosphines were also evaluated and summarized.
手性席夫碱配体是一类重要的、结构上可设计调控的有机配体。
Chiral Schiff bases are a class of the important organic. Ligands and could be designed and synthesized in different structures.
综述了具有独特结构的二茂铁手性膦配体的合成及应用。
The paper reviews the synthesis and application of the unique ligands, which contain the structure of ferrocene chiral phosphine.
第二部分描述了新的手性环状ON NO -型配体的设计合成、表征和在不对称转移氢化反应中的应用。
The second part of this thesis fouses on designed synthesis, characterization of new chiral cyclic ONNO-type ligand and application in asymmetric hydrogenation.
手性氨基-羟基化合物是一类用于催化不对称合成和手性辅助合成的重要配体。
Chiral amino-hydroxy compounds have been proved to be a very efficient class of ligands in a variety of catalytic asymmetric syntheses and chiral auxiliary synthesis catalyzed by metallic ions.
手性氨基-羟基化合物是一类用于催化不对称合成和手性辅助合成的重要配体。
Chiral amino-hydroxy compounds have been proved to be a very efficient class of ligands in a variety of catalytic asymmetric syntheses and chiral auxiliary synthesis catalyzed by metallic ions.
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