... 恒容热 heat at constant volume 恒外压constant external pressure 恒压摩尔热容molar heat capacity at constant pressure ...
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I mean maybe up the street we whisper, but here we know it. And, so here is a different kind of system where we have a constant external pressure.
或许在街上你们低声细语,但在这里不应该这样,这是另一个系统,我们有一个恒定的外压强。
I mean maybe up the street we whisper, but here we know it. And, so here is a different kind of system where we have a constant external pressure.
或许在街上你们低声细语,但在这里不应该这样,这是另一个系统,我们有一个恒定的外压强。
This piston is being brought out, so we expect 0 the work to be negative, negative. And we start o V2 ut with zero volume. We end up with a volume p2 of V2, and the external pressure is constant to p2.
所以我们可以想象功是负的,开始的时候体积是,最终的容积是,外界的压力恒为。
So this isn't the most useful form that we can have, but what we'll see shortly is that from this, we can then derive further criteria for essentially any set of variables or any set of external constraints, like constant temperature or pressure or volume and so forth that we might set.
所以这不是我们所能得到的最有用的形式,但是我们会很快看到,我们能够进一步推导出包含任意变量,或者任意约束的自发过程判断标准,比如说恒定的温度,压强,体积或者其他我们能够给出的约束。
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