It has shown that less 1, 2-unit content corresponds to lower potential barrier of internal rotation and hence to lower energy of rotational isomerization.
进一步的研究表明,低1,2-链节含量对应着较低的分子链内旋转势垒和内旋转异构化能。
In the solar energy transfer and storage system, the isomerization of norbornadiene and quadricyclane is an important reaction.
在太阳能转换与储存体系中,降冰片二烯光异构化合成四环烷是非常重要的一个反应。
The reaction pathways of 1,2-hydrogen migration isomerization on the potential energy face have been calculated by the quantum chemistry, MNDO method.
采用量子化学MNDO法,计算了氟代甲酰胺和N—氟代甲酰胺的1,2—氢迁移异构化反应势能面上的反应路径。
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