The London Symphony Orchestra will also present the world premiere of Mark-Anthony Turnage's At Sixes and Sevens, a new cantata featuring texts by the Pulitzer Prize winning poet Paul Muldoon.
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Smith took the South African bowling apart in his 105 not out, hitting 15 fours and two sixes in only 135 minutes at the crease.
Mascarenhas was in particularly good fettle, hitting eight fours and two sixes to reach 75 not out at the close.
With Chris Tremlett out of contention because of soreness in his foot, Jon Lewis was given his first England opportunity since January, preferred to Dimi Mascarenhas who hit five sixes in 52 in the defeat at Bristol and was fit again after injury.
Solanki and Darren Maddy made decent enough progress, picking up sixes each before the latter was pouched at mid-on off Irfan Pathan.
Chris Cairns and Chris Read quickly followed as the run-rate slowed in the middle overs, with Voges pulling Du Plessis to the waiting Flintoff at deep mid-wicket, leaving Mark Ealham to hit two sixes in a late cameo of 28 off 21 balls.
However, he could not maintain his momentum at the turn and shot a 43, including two double-bogey sixes and three other dropped shots.
He smashed seven boundaries and two sixes on an uncharacteristically sluggish pitch in Brisbane, but finding support at the non-striker's end proved more difficult.
Bell, playing at three, posted his fifth successive 50 and Collingwood managed a couple of sixes off Holland before the tourists decided over lunch it was time to give Tremlett, Bresnan and Shahzad another opportunity with the ball.
Bopara, bravely defying his thumb injury to bat at seven, lofted Powar down the ground for four and Collingwood launched successive big sixes off Tendulkar.
He played back to a good-length ball and edged to Mark Wagh at first slip after a 170-ball innings which contained 12 fours and two sixes.
It was a display of batting that brought to mind the famous over at The Oval last September when he hit India's Yuvraj Singh for five sixes in an over.
But with Herath gritting it out at the other end, McKenzie took charge, dominating the strike and hitting two sixes over square leg off Adams, before a third sealed the match.
Pothas struck Keedy for two sixes on the way to his highest score of the season before he swung at a Chapple delivery, with Flintoff holding on to a waist-high slip catch.
He cracked 25 fours and two sixes in a majestic 176 not out as the visitors closed on 346-2 at Cheltenham College.
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At the start of the over, Kenya required 19 runs to win but the experienced Odoyo hit two sixes and two fours in four dramatic balls to end the contest and leave the Irish shellshocked.
But the West Indies skipper, who hit eight sixes in a stunning 80 from 43 balls in the third match of the series, fished at a good one from Anderson third ball and was comfortably caught by Flintoff at second slip.
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