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Eminem will perform music from his new album Relapse and Kings of Leon will play their hit Use Somebody.
BBC: Ben Stiller to receive MTV honour
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Snow Patrol, Kings of Leon and Celine Dion followed, with Status Quo at number eight with their hits collection.
BBC: Pop divas enjoy chart dominance
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Kings Of Leon beat off competition from The Verve, Metallica, Muse and Rage Against The Machine to win the best festival headline act.
BBC: Newsbeat - Music - Glasto wins at UK festival awards
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Current chart toppers Kings Of Leon, who toured with U2 on their recent Vertigo world jaunt, came in for special praise from guitarist, The Edge.
BBC: Newsbeat - Music - U2 fear The Killers and Coldplay
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Instead of jumping into bed as fast as they can, they sit on the ground and sing Kings of Leon's "Use Somebody" to one another.
WSJ: Star-Crossed Teens Clueless in Verona
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The Grammys are old hat for rock band Kings of Leon.
FORBES: Homes of Grammy Nominees
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The former went to "Use Somebody" by Kings of Leon.
NPR: Beyonce, Swift Big Winners At Lavish Grammys
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But that was more than 11, 500 behind Kings of Leon.
BBC: Kings overrule Sir Cliff in chart
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It's a novel about the steamy love affair between a college student and a billionaire businessman, littered with contemporary references to Apple computers, personal trainers and songs from bands like Snow Patrol and Kings of Leon.
WSJ: How Kindle, Nook and iPad Fuel Sales of Erotica for Women