Ballack drilled the spot kick straight down the middle after Douglas committed himself early.
Gomes duly saved Bent's spot kick and soon afterwards Huddlestone thumped home the clinching second.
The Portuguese picked himself off the floor to slam the spot kick into the net.
Prior to Balotelli's late spot kick the game burst to life in nine second half minutes.
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But after Darren Carter handled in the box, Hoolahan tried to chip his spot kick past Turner, who easily saved.
Daly stepped up to take the spot kick, but his tame effort was palmed clear by Kello.
Eggert Jonsson pulled down Cadamarteri, but the substitute's spot kick was too close to Kello, who parried clear.
Gael Kakuta missed the crucial spot kick as Rovers won the shoot-out 4-3.
Gallacher replaced Smart but was unable to prevent Adams stroking the spot kick into the corner of the net.
Tardif then saved Dave Brammer's first spot kick for Crewe before tipping the second from Kenny Lunt on to the crossbar.
Blayney made to good save to keep out Rowe's spot kick on 33, awarded for David Armstrong's push on Andy Graham.
It was a poor spot kick from Saha, whose effort lacked power and was struck at a good height for the keeper.
Tajikistan appeared set to make the breakthrough after being awarded a penalty, only for captain Samad Shohzukhurov to waste the resulting spot kick.
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Stuttgart's veteran goalkeeper Jens Lehmann saw red as he conceded the late spot kick, stepping on the foot of Mainz striker Aristide Bance.
Ancelotti selected a young side and the match finished 3-3 after extra-time before 18-year-old Gael Kakuta missed his spot kick in the quarter-final tie.
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Boyd netted Rangers' second goal from the penalty spot and Zemmama cast doubt on the validity of the decision to award the spot kick.
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Wayne Rooney edged United ahead with a spot kick three minutes later only for Adam Le Fondre to restore parity in the 19th minute.
Placente brought down striker Patrick Kluivert in the 60th minute for a penalty and was relieved to see goalkeeper Hans-Joerg Butt save Riquelme's spot kick.
Ged Smith was tripped by Coventry defender Carl Winterbottom inside the box, and Sean Paterson sent the keeper the wrong way from the spot kick.
Holt stepped up to convert in Tuesday's 3-2 win at Leicester after Hoolahan missed his second spot kick of the season against Preston on Saturday.
The second spot kick followed another surging run into the Vienna area by Young, although there did not appear to be much contact with Andreas Dober.
He awarded United a penalty when Ronaldo was fairly tackled by Samuel even though none of the home players or supporters appealed for a spot kick.
Lampard kept his cool and sent Pletikosa the wrong way as he steered his spot kick into the left hand corner to spark an unlikely comeback.
Just before the break, Birmingham looked to have won a penalty when Bent was felled by Richard Stearman, but referee Howard Webb ruled out a spot kick.
But Rovers were rewarded in the closing stages when Coppinger was upended by McAllister in the box and Sharp stepped forward to slam home his spot kick.
Falkirk midfielder Scott Arfield tried to place the spot kick low to Trevor Carson's right but the keeper made a fine parry and the ball was cleared.
It was an unnecessary challenge from the Belgian but he was let off the hook when Hart dived to his left to claw away Fabregas's spot kick.
Spain were denied an impressive warm-up win in Sweden as veteran Roland Nilsson struck a late penalty for the hosts to cancel out Josep Guardiola's first-half spot kick.
Helge Payer saved Young's disappointing penalty with a dive to his right but could do nothing to stop Milner's crisp spot kick high to his left after 38 minutes.
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