• The enthalpy entropy compensation effect of these chromatographic process was examined by using of Krugs ANOVA method.

    利用热力学方法,考察这些芳香化合物及其异构体在各种色谱柱上分离过程焓-补偿现象

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  • There's a balance here between ordinary energy or enthalpy and entropy.

    通常所说的能量或者自由之间存在一个平衡

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  • The changing law of retention index with temperature from chromatographic thermal function resulted from the variation of the different entropy and enthalpy during the chromatographic separation.

    色谱热力学函数分析了保留指数温度变化规律主要原因是由于在色谱分离过程中不同熵变焓变所造成的。

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  • The solvent effects, the compensation of the activation enthalpy, and the activation entropy were discussed.

    溶剂效应焓-补偿作用进行了讨论

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  • Calculation and prediction of the enthalpy and entropy of helium-3 are attempted by using the modified quantum version principle of corresponding states.

    作为尝试采用改进量子对应原理,对- 3的热力学性质进行了计算预测

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  • Expressions of entropy, enthalpy and Gibbs function are formulated by exterior differential derived from second law of thermodynamics.

    热力学第二定理出发利用微分构造了以及吉布斯函数表达式

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  • The standard heat capacity, entropy, sublimation enthalpy of graphite.

    升华等热力学函数,并与实验值进行了比较。

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  • Additionally, enthalpy and entropy both contributed to enantioseparation when mobile phase was acetonitrile.

    流动纯乙腈对对映体的拆分贡献

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  • The adsorption enthalpy change, free energy change, entropy change for the phenylacetic acid adsorbed by 3 resins were calculated, and the reasonable explanation was made to the adsorption behavior.

    对苯乙酸3种树脂吸附吸附自由变、吸附变也了计算对吸附行为作了合理解释

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  • Estimations of the isosteric enthalpy of adsorption, free energy, and entropy of adsorption are reported and, the adsorption behaviors are reasonably interpreted.

    对酚类化合物被种树脂吸附吸附自由、吸附也作了测试,吸附行为作了合理解释

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  • The importance to master the calculation method for physical enthalpy, entropy and exergy of light hydrocarbons in various states in petrochemical enterprises were pointed out.

    指出石化企业掌握不同状态下轻烃类物理计算方法重要意义

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  • The effect of temperature on the inhibition efficiency is attributed to the entropy change rather than the enthalpy effect.

    温度缓蚀效率影响由于效应不是效应。

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  • Furthermore, we have obtained the relations accounting for the size and shape dependent melting entropy and melting enthalpy of nanoparticles with free and non-free surface.

    进一步推导出预测自由表面纳米微粒镶嵌熔点基体中基体形成共格界面的非自由表面纳米微粒熔解和熔解的计算公式。

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  • Even though the signs of the enthalpy changed, and the signs of the entropy changed because it's a combination of the two that matters.

    即使自由焓符号发生变化的符号也会发生变化,因为部分起作用。

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  • Standard molar adsorption Gibbs function, standard molar adsorption entropy and standard molar adsorption enthalpy are derived.

    求出了标准摩尔吸附吉布斯函数、标准摩尔吸附标准摩尔吸附

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  • The standard molar heat capacity, standard molar entropy and standard molar enthalpy increased with temperature evidently as quadratic function.

    温度升高标准摩尔、标准摩尔、标准摩尔二次函数增大。

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  • The enthalpy effect and the entropy effect of a process are used to discover the essence of Gibbs free energy criterion with actual examples.

    通过实例,运用过程效应效应,揭示布斯自由判据本质,从而引出其他特定过程对应方向性的判据。

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  • The existence of enthalpy-entropy compensation was also confirmed, and the compensation temperature was found to be a function of absolute temperature, Tc(T).

    蛋白保留过程存在—熵补偿并且补偿温度实验温度函数

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  • The molar enthalpy of solution was positive and the molar entropy was negative.

    氢气在液体中的摩尔溶解焓,摩尔溶解

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  • The formation enthalpy, free enthalpy and entropy of the complex have been calculated by equilibrium constants at different temperatures.

    根据不同温度下平衡常数计算络合物生成、生成自由

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  • This article adopts Yu function method and LKP state equation to calculate enthalpy and entropy, compares the calculated results with experimental results and estimates the precision of the methods.

    本文使用函数LKP状态方程热物性参数进行计算计算结果国外实验结果进行对比判断精确程度

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  • The sorption Enthalpy, Free Energy and Entropy of mercury adsorbed on two kinds peats were calculated by using the thermodynamics functions and equations.

    最后讨论了泥炭吸附热力学基本原理由此所产生的汞对沼泽湿地环境生物的效应。

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  • Free Energy, Enthalpy, and Entropy.

    自由以及

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  • Free Energy, Enthalpy, and Entropy.

    自由以及

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