In the early 1850s, Angstrom, up at the University of Uppsala in Sweden was conducting experiments on atomic hydrogen.
在19世纪50年代的头几年,阿姆斯特朗,那时还在瑞典的乌普萨拉大学里,做了一个有关氢原子的实验。
This is the diagram taken right from your text, there are the two electrodes coming in and this is atomic hydrogen in the gas tube.
这是从教科书上复制下来的图表,这里有两个电极进来,这是气体管中的氢原子。
Hydrogen, we can first draw in our atomic electrons.
氢原子,我们可以先画出原子电子。
He measured the line spectra of atomic hydrogen.
测量了氢原子的线光谱。
Gee, I wonder if I could come up with a set of transitions occurring inside atomic hydrogen Just right match that what Angstrom measured back in 1853.
嘿!我想知道我是否可以想出,发生在氢原子内的,一系列的跃迁,正好符合,阿姆斯特朗在1853年测得的东西。
Take the fattest marking pen you have, scratch that out and replace it with atomic hydrogen.
用你最粗的笔把它划掉,再用氢原子代替它。
A couple of other things about hydrogen: hydrogen also, like other elements, has isotopes and we already saw that in 1766, Cavendish isolated atomic hydrogen and enunciated some of its properties.
一些关于氢的东西:,氢气,就像其他元素一样,有同位素,人们在1766年就发现了这一点,卡文迪许分离出原子氢,并且阐述了它的一些性质。
That is the ground state energy of atomic hydrogen.
同时也是氢原子基态的能量值。
H We've been talking about atomic hydrogen, H.
我们讨论的原子氢。
This is the 1s. And, just to be clear, this is the 1s atomic orbital in atomic hydrogen.
说清楚,这是原子氢的1s原子轨道。
It is a double column, You can see, it starts with hydrogen and goes to mercury in ascending order of atomic mass.
双纵栏,你们看到,从氢开始,然后到水银,按原子质量的升序排列。
That is the electron in its lowest orbit, to the nucleus of atomic hydrogen.
那就是氢原子原子核外电子,最低轨道到情况。
in atomic hydrogen, is it fast? Is it slow?
在氢原子里,速度是快还是慢?
Because only atomic hydrogen has that set of lines which means I could then take the spectra of gas phase species and use that information to identify.
我在这抬头看看然后离开,那就是氢原子,那就意味着,我可以测定,气相种类的光谱并且运用那个信息来鉴定。
But, it could be not just atomic hydrogen.
但是,它不能仅仅是原子氢。
OK, atomic hydrogen, one proton, one electron.
原子氢,单个质子,单电子。
This is for atomic hydrogen gas.
但这只是针对气态氢原子的情况。
So you can see here in this slide we have the atomic orbitals for the two hydrogen atoms, each of them have one electron in them, hydrogen has one electron in a 1 s orbital.
从这个幻灯片你们可以看到我们,有这两个氢原子的原子轨道,每个上面有个电子,氢原子上面有一个电子在1s轨道上。
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