But it is interesting. Let's just, for an order of magnitude say what happens for ground state electron in atomic hydrogen?
但行星模型其实挺有趣的,按照重要的先后顺序,我们来猜想一下,氢原子中的基态电子会发生些什么?
In the early 1850s, Angstrom, up at the University of Uppsala in Sweden was conducting experiments on atomic hydrogen.
在19世纪50年代的头几年,阿姆斯特朗,那时还在瑞典的乌普萨拉大学里,做了一个有关氢原子的实验。
Hydrogen, we can first draw in our atomic electrons.
氢原子,我们可以先画出原子电子。
In other words, just want to know where the electron is somewhere within the shell radius of the ground state of atomic hydrogen anywhere.
换言之,我只是想知道,电子在哪,可以在氢原子基态下的半径,里面的任何地方。
If you look on the Periodic Table this is 598 atomic hydrogen. And, sure enough, there is 13.598, which is this number here in electron volts.
如果你查找元素周期表上的氢原子,毫无疑问,它的电离能就是13。,这个数值也是电子伏的值。
He had a tube with electrodes potted in it filled with atomic hydrogen. And by applying a voltage, he was able to get the gas to glow.
那是个装满了氢原子并含有电极的管子,通过增加一个电压,他让气体燃烧起来了。
Now I have lambdas associated with transitions between energy levels in atomic hydrogen.
现在我把波长和,氢原子中的,能级跃迁联系起来。
This is the diagram taken right from your text, there are the two electrodes coming in and this is atomic hydrogen in the gas tube.
这是从教科书上复制下来的图表,这里有两个电极进来,这是气体管中的氢原子。
It is the value of the radius of the ground state electron orbit in atomic hydrogen.
它就代表氢原子基态电子,的轨道半径。
He measured the line spectra of atomic hydrogen.
测量了氢原子的线光谱。
We saw the Schr?dinger equation for atomic hydrogen, but you can write it for more complex systems.
我们看过原子氢的薛定谔方程,但其实我们能把他用在更复杂的体系。
Gee, I wonder if I could come up with a set of transitions occurring inside atomic hydrogen Just right match that what Angstrom measured back in 1853.
嘿!我想知道我是否可以想出,发生在氢原子内的,一系列的跃迁,正好符合,阿姆斯特朗在1853年测得的东西。
Take the fattest marking pen you have, scratch that out and replace it with atomic hydrogen.
用你最粗的笔把它划掉,再用氢原子代替它。
A couple of other things about hydrogen: hydrogen also, like other elements, has isotopes and we already saw that in 1766, Cavendish isolated atomic hydrogen and enunciated some of its properties.
一些关于氢的东西:,氢气,就像其他元素一样,有同位素,人们在1766年就发现了这一点,卡文迪许分离出原子氢,并且阐述了它的一些性质。
I just burst in now, I look up there and go that's atomic hydrogen.
我现在突然出现,我在这抬头看看然后离开,那就是氢原子。
K/4 We will do it for atomic hydrogen. It is K over four.
在氢原子里这样计算时。
That is the ground state energy of atomic hydrogen.
同时也是氢原子基态的能量值。
H We've been talking about atomic hydrogen, H.
我们讨论的原子氢。
This is the 1s. And, just to be clear, this is the 1s atomic orbital in atomic hydrogen.
说清楚,这是原子氢的1s原子轨道。
So we are going to put atomic hydrogen Z equals one, 1 ground state n equals one.
氢原子Z等于,基态n也等于。
It is a double column, You can see, it starts with hydrogen and goes to mercury in ascending order of atomic mass.
双纵栏,你们看到,从氢开始,然后到水银,按原子质量的升序排列。
That is the electron in its lowest orbit, to the nucleus of atomic hydrogen.
那就是氢原子原子核外电子,最低轨道到情况。
in atomic hydrogen, is it fast? Is it slow?
在氢原子里,速度是快还是慢?
Because only atomic hydrogen has that set of lines which means I could then take the spectra of gas phase species and use that information to identify.
我在这抬头看看然后离开,那就是氢原子,那就意味着,我可以测定,气相种类的光谱并且运用那个信息来鉴定。
But, it could be not just atomic hydrogen.
但是,它不能仅仅是原子氢。
OK, atomic hydrogen, one proton, one electron.
原子氢,单个质子,单电子。
This is for atomic hydrogen gas.
但这只是针对气态氢原子的情况。
So you can see here in this slide we have the atomic orbitals for the two hydrogen atoms, each of them have one electron in them, hydrogen has one electron in a 1 s orbital.
从这个幻灯片你们可以看到我们,有这两个氢原子的原子轨道,每个上面有个电子,氢原子上面有一个电子在1s轨道上。
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