This device was used in the spy movie "Thunderball" about British secret agent James Bond.
VOA: special.2009.01.14
so you can see that there is going to be two sets in antibonding, three sets in bonding for a net of one, giving us the single bond.
因此你能看到,反键轨道上有两组,三组成键,得到一组净成键,所以成的是单键。
Bond allocations had increased by more than could be explained by the increase in bond prices over the course of the year.
同时资产配置中的债券投资比重,以高于当年债券价格上涨的速度,有了显著增加
In the weekly Republican message, Bond said the American people have a right to know where the detainees are going.
VOA: standard.2009.05.09
And if we put that in our bond here, we have 1, 2, 3 bonds, plus we have one lone pair left over.
如果我们把它们放到键里,我们有1,2,3个键,还剩下一对孤对在这里。
part of the James Bond action series. One of Dean's starring roles came in the 1990 film, "Big Bad John."
VOA: standard.2010.06.14
Likewise, the element that is a good electron acceptor in an electron transfer reaction is going to be the element that is going to hog the electrons in a covalent bond.
同样的,这个元素在一个电子转移反应中,是个很好的受赠者它将成为在共价电子,中吸引电子的元素。
Senator Kit Bond of Missouri told Fox News Sunday many of those returned to Yemen are now active in al-Qaida.
VOA: standard.2010.01.03
Socrates, in other words, has broken the bond of tradition and traditional authority that holds the ancient city and the ancient family together.
苏格拉底,其实已经摧毁了,传统与传统权威间的联系,那可是维系古代城邦,与古代家庭的力量。
Fellow-Republican Senator Kit Bond of Missouri blasted the president for recent comments in which he stressed the need for an exit strategy from Afghanistan.
VOA: standard.2009.11.23
In contrast, the dissociation energy of a bond for hydrogen, and molecular hydrogen is everywhere around us, we see 432 kilojoules per mole.
相反,氢分子在我们周围到处都是,一个氢分子的离解能,是432千焦每摩尔。
Let's re-draw this, so it looks a little bit neater, where we have a triple bond in the middle instead, and again, we need our negative 1 charge there.
让我们重写这个,这样看起来更整洁一点,我们有一个三键在中间,同样地,我们这里需要一个负电荷。
So there's not a lot of room in the government bond market or other high-quality bond markets to generate excess returns.
所以对于政府债券或者优质债券,超额收益的空间不大
It's much more relevant to set our zero point energy as the separation of a bond in terms of talking about the reactions that we'll usually be dealing with here.
更好的是把零点能定在,键断裂的时刻,在讨论化学反应的时候,而我们以后将经常遇到化学反应。
Well, if it is a good electron donor in an electron transfer reaction, if the same element finds itself in a covalent bond, it is going to be a good electron donor, although it is not full transfer.
如果它是一个在电子反应中,的好捐赠者,如果相同电子发现他在共价电子里,它将成为一个好的捐赠者,虽然没有完全转换。
A good example of that is CH4, because the CH bond is polar but symmetrically disposed in space.
甲烷就是一个很好的例子,因为极性键是,空间对称的。
We can also think about the distance, the bond distance. So, which would you say is going to be shorter in this case?
我们还可以考虑一下距离,键的距离那么,大家认为其中哪一个键会更短一些?
The yield-to-maturity on an indexed bond is already in real terms because the coupons are indexed to inflation.
这种债券的到期收益率,就是实际收益率,因为票息已经被通胀指数化了
We're already using it up in this pi bond here, so that means we're limited to only two other spots on the molecule, so we have three.
我们已经把它用到这个π键里去了,所以这意味着,我们在分子里只剩下两个位置,所以一共是三个。
So it's very important to be keeping in mind that any time you see a double bond, you have a pi bond there, so you're not going to see any rotation around the bond axis.
所以你们要记住,任何时候你们看到一个双键,这里面有π键,你们不会看到关于键轴的任何转动。
As we see a little bit later, I could talk about the carbon-hydrogen bond in methane where there is a plurality of bonds. In this case, there is only the one bond but I just want to get the formulas.
因为我们后来看到一点点,我能讨论甲烷中的碳氢共价键,那有许多共价键,这种情况下,这只有一条共价键,但我想得到氟。
The first one will be above and below the bond axis is where we'll see the electron density, and the second will be perpendicular to that, so it will be a density in front of and behind the bond axis.
第一个是在键轴之上和之下,我们可以看到电子密度,另外一个垂直于它,所以在键轴之前和之后有电子密度。
So notice a difference in these structures, is this has an n h bond whereas this has an o h bond.
注意它们之间的有一点不同,那就是一个有氮氢键,而另一个有氧氢键。
So even though we see a nodal plane down the center, I just want to really point out that it's only when we have a nodal plane in the internuclear or the bond axis that we're calling that a pi orbital.
虽然在中间有个节面,我想要指出的是,只有节面在核间轴,或者键轴上时,我们才叫它π轨道。
All right, so that's really all there is to thinking about valence bond theory in terms of the most simple explanation here.
好了,这就是,价电子轨道理论的,最简单的解释。
The Born-Haber cycle was designed to allow us to calculate the energetics of, in particular,the ionic bond.
伯恩哈勃循环,可以让我们计算能量,特别是离子键的。
So in order to rotate a double bond, you have to actually break the pi bond, so essentially what you're doing is breaking the double bond.
为了能够旋转双键,你必须打破一个π键,本质上我们要做的就是打破双键。
And we can also talk about the bond length, so we might be interested in what the bond length is, what the distance between these two nuclei are.
另外一点就是键长,我们对键的长度也感兴趣,也就是两个原子核之间的距离。
In valence bond theory, the focus is on discussing the bonds, but it should look very familiar to you, because there's two types of bonds that we want to discuss here.
在价电子成键理论中,所关注的是讨论成键,但这对于你们来说应该很熟悉,因为这是我们要讨论的两种键。
And by that what we mean is that they're absolutely identical, and it turns out that this here is not a double bond, it's not a single bond either, it's actually something in between.
这意味着它们是绝对完全相同的,实际情况应该是这不是一个双键,这也不是一个单键,而是介于两者之间的状态。
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