It's much more relevant to set our zero point energy as the separation of a bond in terms of talking about the reactions that we'll usually be dealing with here.
更好的是把零点能定在,键断裂的时刻,在讨论化学反应的时候,而我们以后将经常遇到化学反应。
All right, so that's really all there is to thinking about valence bond theory in terms of the most simple explanation here.
好了,这就是,价电子轨道理论的,最简单的解释。
The yield-to-maturity on an indexed bond is already in real terms because the coupons are indexed to inflation.
这种债券的到期收益率,就是实际收益率,因为票息已经被通胀指数化了
So the point is, this balance between energy thatyou could think of as say bond energies in chemical reactions, and entropy that you can think of in terms of disorder, how many different possible combinations or configurations of something wrong, will dictate where the equilibrium lies.
关键在于,这种能量与熵之间的平衡,确定了平衡的条件,在化学中能量涉及键能,而熵和无序有关,即有多少可能的不同组合或者形位,二者的平衡会告诉我们平衡态是什么样子。
So in terms of thinking about ethane, we actually have two bond types that we're going to be describing just in terms of the carbon-carbon bond and then the carbon h bonds.
对于乙烷,我们有两种键,我们继续讨论一下,碳碳键,和碳氢键。
/2 So this would mean the bond order is equal to 1/2, and in terms of valence electrons, how many bonding valence electrons do we have?
这意味着键序等于,对于价电子,有多少个成键价电子?
That's the huge force that we're talking about in terms of making a bond stable, but there are also repulsive forces, so you can imagine we're going to have electron-electron repulsion between the two electrons if we're bringing them closer together.
正是这个非常强的力,使得我们所讨论的这个键能够稳定存在,但是其中还有排斥力存在,大家可以想象一下,我们会有电子与电子之间的排斥力,如果让它们离得更近。
If I'm going to be active in terms of managing my portfolio, should I spend my time and energy trying to beat the bond market?
如果我想主动地管理我的投资组合,是否应投入时间和精力,专注于战胜债券市场呢
So, what this lets us do now is directly compare, for example, the strength of a bond in terms of a hydrogen atom and hydrogen molecule, compared to any kind of molecule that we want to graph on top of it.
因此,这让我们现在可以做到直接进行比较,比如,将一个氢原子,和一个氢分子的键的强度,与任何其它类型的分子进行比较,我们只需要把它的曲线也画在这幅图上。
So in terms of naming our o h bond, good, it's right here.
对于OH键的命名,很好,在这里。
So in terms of the carbon hydrogen bond, it's a sigma bond, - because we define it -- any time we are bonding to an atom, we have to keep redefining our bond axis to whatever two atoms we're talking about.
对于碳氢键,它是sigma键,因为我们定义它-,任何时候我们有原子成键,我们要重新定义键轴方向,为我们所讨论的两个原子方向。
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