• So, you remember from last time radial nodes are values of r at which the wave function and wave function squared are zero, so the difference is now we're just talking about the angular part of the wave function.

    你们记得上次说径向节点在,波函数和波函数的平方,等于零的r的处,现在的区别是我们讨论的是,角向波函数。

    麻省理工公开课 - 化学原理课程节选

  • So, we can do that by using this equation, which is for s orbitals is going to be equal to dr 4 pi r squared times the wave function squared, d r.

    用这个方程,对于s轨道,径向概率分布,4πr的平方,乘以波函数的平方,这很容易理解。

    麻省理工公开课 - 化学原理课程节选

  • So we have the operationon the wave function in terms of r, theta, and phi and remember this e is just our binding energy for the electron, and we get back out this wave function.

    我们用r,θ,φ来表示,将算符作用于波函数,而且记住e仅仅是电子结合能,然后后面加上波函数。

    麻省理工公开课 - 化学原理课程节选

  • l But now we need to talk about l and m as well. So now when we talk about a ground state in terms of wave function, we need to talk about the wave function of 1, 0, 0, and again, as a function of r, theta and phi.

    但我们现在需要讨论,和m,现在当我们讨论,波函数的基态时,我们讨论的,是1,0,0的波函数,同样的,它也是r,theta和phi的函数。

    麻省理工公开课 - 化学原理课程节选

  • We call that a node, r and a node, more specifically, is any value of either r, the radius, or the two angles for 0 which the wave function, and that also means the wave function 0 squared or the probability density, is going to be equal to zero.

    节点就是指对,于任何半径,或者,两个角度,波函数等于,这也意味着波函数的平方或者概率密度,等于,我们可以看到在1s轨道里。

    麻省理工公开课 - 化学原理课程节选

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