For a real gas it depends on more than the temperature STUDENT: Are there any other constraints similar to that .
而对实际气体,这是不对的,它的内能不仅仅依赖于温度,学生:有其他,类似的约束吗?
dT/dp is mu JT. So for a real gas like air, this is a positive number. It's not zero.
所以对于像空气这样的真实气体,这是一个正数,不等于零。
This needs to be stressed that this is the ideal gas case. Now regular gases, real gases fortunately as I said, don't obey this.
需要强调的是这是对理想气体而言的,普通气体,真实气体,就像我说过的,不遵循这个规律,这是非常重要的。
H for an ideal gas is only a function of temperature. This is not true for a real gas fortunately, but it's true for an ideal gas.
不正确的,但是幸运的是,对于理想气体是完全正确的。
When you expand a real gas into vacuum, the temperature goes down.
当一个真实气体,向真空膨胀咱的时候温度会下降。
u=0 And it's approximately equal to zero for all real gas processes.
在所有理想气体绝热过程中Δ,对真实气体近似为零。
For a real gas, that won't be true.
它的内能。
If z is greater than 1, then the real gas means that the atoms and molecules in the real gas are repelling each other and wants to have a bigger volume.
如果Z大于,说明实际气体的分子间斥力较强,体积比理想气体要大,我们可以查表找到。
If you have a real gas and you write du is Cv dT and your path is not a constant volume path, then you are making a mistake. But for an ideal gas, you can always write this. And this turns out to be very useful to remember.
对于真实气体,如果其变化过程,不是恒容的,du=Cv*dT就不成立,但对于理想气体,这条规则永远成立,这一点非常有用,请记住。
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