He said that the percent ionic character, and this is within a bond, not for a compound, for a covalent bond.
他提到离子百分数,是指一根键中,并非一个分子中。
So let's figure out the bond order for our two molecules here that we figured out the electron configuration for.
让我们看看这里,两个分子的键序是多少。
And you would find that the bond energy of the heteronuclear molecule was nowhere on the average of the two.
你将发现,电子相同的分子的总能量,并不是平分的。
So there's not a lot of room in the government bond market or other high-quality bond markets to generate excess returns.
所以对于政府债券或者优质债券,超额收益的空间不大
So, there's actually another way to graph it where we can directly graph the dissociation energy or the bond strengths.
其实,还有另外一种画这个曲线的方式,可以直接画出离解能的大小,或者键的强度。
So what we can actually directly compare is the dissociation energy or the bond strength of nitrogen versus hydrogen.
因此实际上我们可以直接进行比较,对氮分子与氢分子的离解能,或键的强度。
The price of the two-period bond is 1/2 and the price of the one-period bond is 1/.
所以两年期债券的价格是1/^2,一年期债券的价格则是1/
We see that the radius is shorter, so that means that the nitrogen-nitrogen bond is going to be shorter.
我们看到这个距离更短,这就意味着,氮与氮之间的键应该更短。
So if we look at its length, it's actually shorter than a single bond, but longer than a double bond.
因此如果我们看它的键长的话,它实际上比单键更短,却比双键更长。
And we find the same thing for these two atoms here, it's not actually a double bond, it's somewhere between a single bond and a double bond.
而且我们发现这两个原子的情况是一样的,它其实不是一个双键,而是介于单键与双键之间的。
We can know this information even if we just knew that the bond was stronger, we wouldn't need to look at a graph here, because it turns out that if you have a stronger bond, -- that also means that you have a shorter bond -- those two are correlated.
我们依然可以得到上面的信息,即使我们所知道仅仅是这个键更强,我们不需要去看这个图,因为事实上如果你有一个更强的键,这也就意味着你有一个更短的键-,这两点是互相关联的。
So what we see is a bond order of 0, and again, the bond is very, very weak.
我们看到键序是0,同样的,键非常非常的弱。
So let's take a look at what actually happens if we're talking about a carbon-carbon double bond, we're going to have a double bond.
让我们来看一看碳碳双键的情况,例如在乙烷里,我们有个双键。
So we want to have constructive interference to form a bond, where as if we had destructive interference, we would not be forming a bond.
我们需要,相干相长来成键,如果,相干相消了,就不能成键,所以这时候。
Molecular orbital theory, even at this very basic level, allowed us to predict that no, we're not going to see a true bond here, a strong bond.
即使在最基础的层次,分子轨道理论预计,我们不会看到一个键,一个强的键,。
So it's very important to be keeping in mind that any time you see a double bond, you have a pi bond there, so you're not going to see any rotation around the bond axis.
所以你们要记住,任何时候你们看到一个双键,这里面有π键,你们不会看到关于键轴的任何转动。
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