• He said that the percent ionic character, and this is within a bond, not for a compound, for a covalent bond.

    他提到离子百分数,是指一根键中,并非一个分子中。

    麻省理工公开课 - 固态化学导论课程节选

  • So let's figure out the bond order for our two molecules here that we figured out the electron configuration for.

    让我们看看这里,两个分子的键序是多少。

    麻省理工公开课 - 化学原理课程节选

  • And you would find that the bond energy of the heteronuclear molecule was nowhere on the average of the two.

    你将发现,电子相同的分子的总能量,并不是平分的。

    麻省理工公开课 - 固态化学导论课程节选

  • So there's not a lot of room in the government bond market or other high-quality bond markets to generate excess returns.

    所以对于政府债券或者优质债券,超额收益的空间不大

    耶鲁公开课 - 金融市场课程节选

  • So, there's actually another way to graph it where we can directly graph the dissociation energy or the bond strengths.

    其实,还有另外一种画这个曲线的方式,可以直接画出离解能的大小,或者键的强度。

    麻省理工公开课 - 化学原理课程节选

  • So what we can actually directly compare is the dissociation energy or the bond strength of nitrogen versus hydrogen.

    因此实际上我们可以直接进行比较,对氮分子与氢分子的离解能,或键的强度。

    麻省理工公开课 - 化学原理课程节选

  • The price of the two-period bond is 1/2 and the price of the one-period bond is 1/.

    所以两年期债券的价格是1/^2,一年期债券的价格则是1/

    耶鲁公开课 - 金融市场课程节选

  • We see that the radius is shorter, so that means that the nitrogen-nitrogen bond is going to be shorter.

    我们看到这个距离更短,这就意味着,氮与氮之间的键应该更短。

    麻省理工公开课 - 化学原理课程节选

  • So if we look at its length, it's actually shorter than a single bond, but longer than a double bond.

    因此如果我们看它的键长的话,它实际上比单键更短,却比双键更长。

    麻省理工公开课 - 化学原理课程节选

  • And we find the same thing for these two atoms here, it's not actually a double bond, it's somewhere between a single bond and a double bond.

    而且我们发现这两个原子的情况是一样的,它其实不是一个双键,而是介于单键与双键之间的。

    麻省理工公开课 - 化学原理课程节选

  • We can know this information even if we just knew that the bond was stronger, we wouldn't need to look at a graph here, because it turns out that if you have a stronger bond, -- that also means that you have a shorter bond -- those two are correlated.

    我们依然可以得到上面的信息,即使我们所知道仅仅是这个键更强,我们不需要去看这个图,因为事实上如果你有一个更强的键,这也就意味着你有一个更短的键-,这两点是互相关联的。

    麻省理工公开课 - 化学原理课程节选

  • So what we see is a bond order of 0, and again, the bond is very, very weak.

    我们看到键序是0,同样的,键非常非常的弱。

    麻省理工公开课 - 化学原理课程节选

  • So let's take a look at what actually happens if we're talking about a carbon-carbon double bond, we're going to have a double bond.

    让我们来看一看碳碳双键的情况,例如在乙烷里,我们有个双键。

    麻省理工公开课 - 化学原理课程节选

  • So we want to have constructive interference to form a bond, where as if we had destructive interference, we would not be forming a bond.

    我们需要,相干相长来成键,如果,相干相消了,就不能成键,所以这时候。

    麻省理工公开课 - 化学原理课程节选

  • Molecular orbital theory, even at this very basic level, allowed us to predict that no, we're not going to see a true bond here, a strong bond.

    即使在最基础的层次,分子轨道理论预计,我们不会看到一个键,一个强的键,。

    麻省理工公开课 - 化学原理课程节选

  • So it's very important to be keeping in mind that any time you see a double bond, you have a pi bond there, so you're not going to see any rotation around the bond axis.

    所以你们要记住,任何时候你们看到一个双键,这里面有π键,你们不会看到关于键轴的任何转动。

    麻省理工公开课 - 化学原理课程节选

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