• For the carbon, we start with 4 valence electrons, we have 0 lone pair electrons minus 4, and we end up with a formal charge of 0.

    对于碳,我们从四个价电子开始,我们有零个孤对电子,再减去四,最终我们有零个形式电荷。

    麻省理工公开课 - 化学原理课程节选

  • If these bonds were all completely of equal distance apart, whether is was a lone pair or bonding electrons, 5° the angles would be 109 . 5 degrees.

    如果不管它是孤对,还是成键,它们等距分开的话,键角是109。

    麻省理工公开课 - 化学原理课程节选

  • And orbiting around this is a lone electron out at some distance r.

    有一个单电子,在环原子核的轨道上运行。

    麻省理工公开课 - 固态化学导论课程节选

  • So in terms of nitrogen that starts off with a valence number of 5, again we have 2 lone pair electrons in the nitrogen, and again, we have 6 electrons that are shared.

    对于氮来说,我们应该从五个价电子开始,同样,氮也有两个孤对电子,共用电子的个数也一样,是六个。

    麻省理工公开课 - 化学原理课程节选

  • Well, we're talking about a pretty high number here, so to make counting easier, we'll just say 10 lone pairs, because 20 lone pair electrons is the same thing as 10 lone pairs.

    好吧,我们这里讨论的是一个挺大的数,为了数起来更容易,我们就说有十对孤对电子,因为二十个跟十对是一个意思。

    麻省理工公开课 - 化学原理课程节选

  • For the sulfur, we start off with 6 valence electrons, minus 4 lone pair electrons, minus 2, taking in account our bonding electrons, so we end up with a formal charge of 0.

    对于硫,我们从六个价电子开始,减去四个孤对电子,再减去二,算上我们的成键电子,因此最终我们有零个形式电荷。

    麻省理工公开课 - 化学原理课程节选

  • So it looks a lot less messy if we just draw our Lewis structure like this for h c n, where we have h bonded to c triple bonded to n, and then a lone pair on the nitrogen there.

    这看起来整洁了不少,如果我们把氰化氢的路易斯结构画成这样的话,这样我们就有氢与碳之间的单键和碳与氮之间三键,然后还有一对孤对电子在氮这里。

    麻省理工公开课 - 化学原理课程节选

  • And if we talk about chlorine, and both of the chlorines are the same in this case, we start with a valence number of 7 for chlorine, and then we subtract 6, because it had 6 lone pair electrons around each of the chlorine atoms.

    而如果我们讨论氯的话,在这个例子中两个氯的情况都是一样的,从七个价电子开始,然后减去六,因为每个氯原子周围,都有六个孤对电子。

    麻省理工公开课 - 化学原理课程节选

  • So what we see is on ammonia here, 107 we know that it's less than a 109 . 5, it's actually 107, so it's less than a 109 . 5, because of that lone pair pushing down in the bonding electrons.

    我们看到在氨分子里,我们知道它比109.5要小,它是,所以比109。5要小,因为孤对会把成键电子向下推。

    麻省理工公开课 - 化学原理课程节选

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