Our molecular partition function.
我们的分子配分函数。
This is the electronic partition function.
这是电子的配分函数。
In the configurational partition function.
在构型配分函数中。
It's called the canonical partition function.
称为正则配分函数。
OK. So this is your molecular partition function.
好,这就是分子配分函数。
And the system partition function is labeled big Q.
系统的配分函数用Q标记。
Now, qi is just the total molecular partition function.
现在qi是分子总配分函数。
We also know what the vibrational partition function is.
我们也知道振动能的配分函数。
So the molecular partition function is labeled little q.
这里分子的配分函数用q标记。
So now let's figure out our molecular partition function.
现在我们来计算分子的配分函数。
Unnamed objects such as partition function parameters.
未命名对象,如分区函数参数。
You can also look at the molecular partition function itself.
对单个分子的配分函数本身也适用。
We can write the partition function as a sum over energy level.
我们可以把配分函数写成,对能级的求和。
The rotational partition function and thermodynamical properties of hydrogen;
讨论了室温条件下氢的转动配分函数应采用的形式。
So last time, then, you saw how from the canonical partition function, you could get something like the energy.
上节课我们看到了如何,从正则配分函数导出,内能等量。
In other words, if I have an expression for Q, I know the partition function, and I can calculate it at any temperature.
换句话说,如果我得到了Q的表达式,知道了配分函数,我可以计算它在任意温度下的数值。
Through this model and using finite temperature field theory, we can write down the partition function of the system.
通过这一模型加上虚时温度场论就可以写出核物质系统的配分函数。
The partition function of flexible cushion on the bottom of explosive holes was proved by experiments before explosion.
爆前试验证明了钻孔底部柔性垫层的隔震作用。
So it becomes interesting, then, to figure out, how can we write the Helmholtz free energy in terms of the canonical partition function?
这就让我们开始思考,要怎么来表示亥姆霍兹自由能,用正则配分函数?
So now we can just write out the configurational partition function for the molecules and also the canonical partition function for the system.
那么现在我们就能写出,分子构型的配分函数,和系统的正则配分函数。
The grand partition function of intermediate statistics with a standard method is derived to calculate the thermodynamic properties of an ideal free-particle model.
利用现行标准的统计力学方法推导出中间统计的巨配分函数,得到了服从中间统计的理想自由粒子模型的热力学函数。
In statistical physics lectures, the calculation of the configuration partition function of molecule is simplified from double vectors integral to single vector integral.
统计物理教材中分子构型配分函数的计算,一般是将双矢量积分化简为单矢量积分。
In this article, a different view and suggestion are given about hydrogen molecular partition function in teaching material of the thermodynamics and statistical physics.
该文就热力学统计物理教材中仲氢分子配分函数的表达式提出了不同看法,并给出了修改建议。
In consideration of the strong intermolecular interactions in liquids, a hindering factor is introduced to modify the contribution of their rotation and vibration to the internal partition function.
考虑到液体分子间的强相互作用,引入了一个阻障因子,以修正其转动和振动对内配分函数的贡献。
In consideration of the strong intermolecular interactions in liquids, a hindering factor is introduced to modify the contribution of their rotation and vibration to the internal partition function.
考虑到液体分子间的强相互作用,引入了一个阻障因子,以修正其转动和振动对内配分函数的贡献。
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